Fe-Mn-Al-C steels exhibit an outstanding combination of strength and ductility, and the addition of aluminum drastically reduces the density of steels. The low density also offers the advantage of lightweight structures compared with other alloys in practical applications. The addition of aluminum leads to an increased probability of κ-carbide precipitation, which would significantly affect the mechanical properties. This paper aims to review the κ-carbide in Fe-Mn-Al-C steels, including the structure, elastic and magnetic properties of κ-carbide, the precipitation mechanism of κ-carbide involving thermodynamic equilibrium, and the operative deformation mechanism of κ-carbide that governs the mechanical properties. It is hoped that such a comprehensive summarization of the knowledge of κ-carbide will be beneficial for the further development of low-density Fe-Mn-Al-C steels.

On the basis of reiterating the concept of grain boundary engineering (GBE), the recent progress in the theoretical models and mechanisms of twin-related GBE optimization and its effect on the mechanical properties is systematically summarized in this review. First, several important GBE-quantifying parameters are introduced, e.g., the fraction of special grain boundaries (GBs), the distribution of triple-junctions, and the ratio of twin-related domain size to grain size. Subsequently, some theoretical models for the GBE optimization in face-centered cubic (FCC) metals are sketched, with a focus on the model of “twin cluster growth” by summarizing the in-situ and quasi-in-situ observations on the evolution of grain boundary character distribution during the thermal-mechanical process. Finally, some case studies are presented on the applications of twin-related GBE in improving the various mechanical properties of FCC metals, involving room-temperature tensile ductility, high-temperature strength-ductility match, creep resistance, and fatigue properties. It has been well recognized that the mechanical properties of FCC materials could be obviously improved by a GBE treatment, especially at high temperatures or under high cyclic loads; under these circumstances, the materials are prone to intergranular cracking. In short, GBE has tremendous potential for improving the mechanical properties of FCC metallic materials, and it is a feasible method for designing high-performance metallic materials.

A novel steel combining the “quenching and tempering (Q&T)” process was exploited that can achieve the enhancement of austenite by interface migration during tempering the martensitic matrix mixed with films of austenite. A high uniform elongation (12%) combined with high yield tensile strength (1500 MPa) was obtained, which showed distinct advantages over all the other advanced high strength steels under development for a lightweight car body. Furthermore, the effect of austenite on enhancement of ductility in “Q&T” steels with a martensite matrix was elucidated, which suggested that the ductility was promoted by enhancing boundary sliding and delaying work hardening of the martensitic matrix.