The purpose of this study was to evaluate the feasibility of using magnesium and sodium lignosulfonates (LS) in the production of particleboards, used pure and in mixtures with urea-formaldehyde (UF) resin. Polymeric 4,4′-diphenylmethane diisocyanate (pMDI) was used as a crosslinker. In order to evaluate the effect of gradual replacement of UF by magnesium lignosulfonate (MgLS) or sodium lignosulfonate (NaLS) on the physical and mechanical properties, boards were manufactured in the laboratory with LS content varying from 0% to 100%. The effect of LS on the pH of lignosulfonate-urea-formaldehyde (LS-UF) adhesive compositions was also investigated. It was found that LS can be effectively used to adjust the pH of uncured and cured LS-UF formulations. Particleboards bonded with LS-UF adhesive formulations, comprising up to 30% LS, exhibited similar properties when compared to boards bonded with UF adhesive. The replacement of UF by both LS types substantially deteriorated the water absorption and thickness swelling of boards. In general, NaLS-UF-bonded boards had a lower formaldehyde content (FC) than MgLS-UF and UF-bonded boards as control. It was observed that in the process of manufacturing boards using LS adhesives, increasing the proportion of pMDI in the adhesive composition can significantly improve the mechanical properties of the boards. Overall, the boards fabricated using pure UF adhesives exhibited much better mechanical properties than boards bonded with LS adhesives. Markedly, the boards based on LS adhesives were characterised by a much lower FC than the UF-bonded boards. In the LS-bonded boards, the FC is lower by 91.1% and 56.9%, respectively, compared to the UF-bonded boards. The boards bonded with LS and pMDI had a close-to-zero FC and reached the super E0 emission class (≤1.5 mg/100 g) that allows for defining the laboratory-manufactured particleboards as eco-friendly composites.
From modern buildings to public spaces are made of concrete, steel, and glass. These materials increase propagation of sound and the reverberation time. Therefore, furniture should be good sound absorbers in such places. The objective of this study was to ascertain acoustic properties of wood-based materials by determining normal acoustic impedance on the surface and sound absorption coefficients. Experiments were carried out on 17 types of wood-based materials commonly employed in furniture design and manufacture. Investigations were conducted based on the transfer-function method. It was demonstrated that for frequencies between 125 and 500 Hz, the highest capability of sound absorption was determined of low surface layer density and high porosity. Honeycomb panels with paper core absorbed better sounds in the range between 1 and 2 kHz. Panels of considerable external surface irregularities were characterized by the most favorable acoustic properties for the frequency of 4 kHz.
16 December 2016 in European Journal of Wood and Wood Products
The paper investigates the possibility of manufacturing rapeseed particleboards (RPB) which could be used as construction material in eco buildings. Therefore, single-layer particleboards were produced from rapeseed straw particles glued with mixture of 4.4′-methylenediphenyl isocyanate (pMDI) and phenol–formaldehyde (PF) resins in the weight ratio 70:30 (hybrid pMDI/PF resin). The boards were manufactured with density of 650, 600, 550, 500 and 450 kg/m3. Next, their physico-mechanical properties were determined, i.e. modulus of rupture, modulus of elasticity, internal bond and internal bond after the boil test (V-100) and thickness swelling after 24 h soaking in water. The thermal conduction coefficient (λ) and sorption properties in changeable relative humidity conditions were also determined. Based on the obtained results, it was found that rapeseed straw may be a valuable material used in the production of construction particleboards which meet high strength requirements. Boards with density of 650 kg/m3 meet the requirements of EN 312 standard for type P7 boards. It is also possible to decrease their density to 600 kg/m3 (type P5 boards) and even 550 kg/m3 (type P3 boards). However, rapeseed particleboards are characterized by relatively high values of thickness swelling after 24 h of soaking in water. The weaker resistance to humidity has also been confirmed by tests on sorption and desorption of vapour in changeable relative humidity conditions. Nonetheless, an important advantage of these boards is the fact that they are characterized by better thermal insulation than particleboards.
The woodworking industry generates a great amount of bark which has not yet found a wider industrial application. None of the previously conducted research has considered oak bark application (which is one of the most often processed wood species in Poland) as a filler for wood adhesives. Moreover, no studies have determined the properties of bark containing melamine-urea-formaldehyde resin (MUF), which increasingly replaces pure urea-formaldehyde adhesives. Thus, the aim of the study was to determine the possibility of grinded oak bark application as a filler for MUF adhesive in plywood manufacturing. The chemical composition of oak bark was evaluated. Properties of liquid resins, such as viscosity, gel time, pH, and solid content, were determined. Chemical interaction between the filler and resin was assessed with using Fourier-transform infrared (FTIR) spectroscopy. Plywood panels manufactured using MUF adhesive filled with different bark concentrations (10%, 15%, 20%, 25%) were tested in terms of such properties as formaldehyde release and bonding quality. Studies have shown an improvement in liquid resin properties. The course of FTIR spectra did not explain the chemical interaction between the polymer and the filler. The addition of oak bark at a concentration of 15% made it possible to produce plywood panels characterized by reduced formaldehyde release and improved bonding quality.
This work examines the possibility of applying non-modified nanocellulose and nanocellulose functionalized with 3-aminopropyltriethoxysilane (APTES) as a formaldehyde scavenger for commonly used urea-formaldehyde (UF) adhesive. The effect of silanization was determined with the use of Fourier transform infrared spectroscopy (FTIR), flame atomic absorption spectrometry (FAAS), and elemental analysis. Moreover, the ability of cellulosic nanoparticles to absorb the formaldehyde from an aqueous solution was investigated. After homogenization, cured UF adhesives were examined with the use of FTIR, energy-dispersive spectroscopy (SEM-EDS), and the perforator method to determine the content of formaldehyde. Manufactured boards made of rape straw particles and wood particles were tested in terms of their physico-mechanical properties and formaldehyde emission. Studies have shown that the applied method of silanization was effective. Furthermore, in the case of non-modified nanocellulose, no sign of formaldehyde scavenging ability was found. However, the functionalization of cellulosic nanoparticles with APTES containing an amino group led to the significant reduction of formaldehyde content in both the aqueous solution and the UF adhesive. The mechanical properties of both strawboards and particleboards were improved due to the nanocellulose reinforcement; however, no effect of silanization was found. Nevertheless, functionalization with APTES contributed to a decrease in formaldehyde emission from boards, which was not found in the case of the introduction of non-modified cellulosic nanoparticles.
26 August 2020 in Journal of Applied Polymer Science