As a new and promising compression technology for hydrogen gas, the ionic liquid compressor inherits the advantages of the ionic liquid and the hydraulic system. The liquid density is one of the key parameters influencing the fluid flow field, the sloshing of the bulk liquid, and the movement of droplets generated during the compressor operation. An appropriate selection of the liquid density is important for the compressor design, which would improve the thermodynamic performance of the compressor. However, the density of the ionic liquid varied significantly depending on the specific combination of the cation and anions. This paper proposed the methodology to select the optimal liquid density used in the ionic liquid compressor for hydrogen storage. The gas-liquid interaction in the compression chamber is analysed through numerical simulations under varied liquid density values. Results found that the increase in the liquid density promoted the detachment of the ionic liquid from the cylinder cover during the suction procedure and the contact of the bulk liquid on the compressor cover when the gas is compressed in the cylinder during the compression procedure. Both the droplet size and the dimension of the derived gas vortex decreased when the liquid density increased. The lowest mass transfer of hydrogen through the outlet was obtained at the density of 1150 kg/m3. The density of the ionic liquid from 1300 to 1450 kg/m3 is suggested to the hydrogen compressor, taking into account the transient two-phase flow characteristics, the mass transfer, and the total turbulent kinetic energy.
18 July 2021 in International Journal of Minerals, Metallurgy and Materials
Al-Mg-Si based alloys are popular alloys used in the automotive industry. However, limited studies have been performed to investigate the microstructure, deformation characteristics, and deformation mechanism for the semi-solid 6063 alloys. In this study, the cold radial forging method and semi-solid isothermal treatment (SSIT) are proposed in the semi-solid isothermal compression (SSIC) process to fabricate high-quality semi-solid 6063 billets. The effects of deformation temperature, strain rate, and strain on the microstructure, deformation characteristics, and deformation mechanism of the SSIC of cold radial forged 6063 alloys were investigated experimentally. Constitutive equations were established based on the measured data in experiments to predict the flow stress. Results show that an average grain size in the range from 59.22 to 73.02 μm and an average shape factor in the range from 071 to 078 can be obtained in the microstructure after the cold radial forged 6063 alloys were treated with SSIT process. Four stages (i.e., sharp increase, decrease, steady state, and slow increase) were observed in the true stress- true strain curve. The correlation coefficient of the constitutive equation was obtained as 0.9796 while the average relative error was 5.01%. The deformation mechanism for SSIC of cold radial forged aluminum alloy 6063 mainly included four modes: The liquid phase flow, grain slide or grain rotation along with the liquid film, slide among solid grains, and the plastic deformation of solid grains.