An analysis method for phenolic compounds in waste was developed, and its contents and leaching concentrations were measured to investigate the concentration and distribution of phenolic compounds in waste in South Korea. The EPA 8041 method was applied; thirteen phenolic compounds were derivatized and analyzed simultaneously using pentafluorobenzylbromide (PFBBr). Leaching pretreatment was performed using Korea’s leaching test method. For content pretreatment, extraction and derivatization were performed by applying EPA 3550C. An analysis was conducted using GC-MS. Fifty samples were collected from industrial waste in Korea, and six waste types (wastewater sludge, organic sludge, process sludge, waste foundry sand, waste soil, and waste sand) were selected for research. In the analysis results, seven phenolic compounds (2-Chlorophenol, 4-Chloro-3-methylphenol, 2,4-Dichlorophenol, 2,6-Dichlorophenol, 2,4,5-Trichlorophenol, 2,4,6-Trichlorophenol, and 2,3,4,6- Trichlorophenol) were not detected in the samples. When leachate was analyzed, organic sludge exhibited the highest total phenolic compound content of 18.8 mg/L, with nonylphenols (NPs, 14.4 mg/L) and p-Cresol (0.4 mg/L) showing the highest concentrations. In the content analysis results, the highest total phenolic compound content of 119.3 mg/kg was detected from wastewater sludge with bisphenol A (43.8 mg/kg), phenol (27.8 mg/kg), pentachlorophenol (18.1 mg/kg), o-Cresol (2.8 mg/kg), and m-Cresol (0.5 mg/kg) exhibiting the highest concentrations. When the analysis results were compared with domestic and overseas recycling criteria, the leachate criterion (1 mg/L) was exceeded by 17 samples out of 50, whereas the content criterion (4 mg/kg) was exceeded by 26 samples. This indicates that it is necessary to prepare countermeasures regarding emission source management.