The electron absorption-, photoluminescence- and electron paramagnetic-resonance spectra of Mn3+ in red beryl from Wah Wah Mountains (Utah USA) and of pink- and purple vesuvianite from Jeffrey Mine (Asbestos, Canada) were measured at room- and low temperatures. The crystal field stabilization energies are equal to 130.9 kJ/mol for the red beryl, and 151.5–158.0 and 168.0 kJ/mol for for the pink- and the purple vesuvianite, respectively. The red photoluminescence of Mn3+ was not intensive either at room- or at low temperatures. The high Mn content in the crystals caused the emergence of an additional emission band and short photoluminescence-decay lifetimes. The latter are only 183 μs for beryl and 17 μs for vesuvianite.
A FePt-based hard-magnetic nanocomposite of exchange spring type was prepared by isothermal annealing of melt-spun (atomic percent) ribbons. The relationship between microstructure and magnetic properties was investigated by qualitative and quantitative structural analysis based on the x-ray diffraction, transmission electron microscopy, and Mössbauer spectrometry on one hand and the superconducting quantum interference device magnetometry on the other hand. The microstructure consists of hard-magnetic grains (15–45 nm in diameter) dispersed in a soft magnetic medium composed by A1 FePt, , and boron-rich (FeB)PtNb remainder phase. The ribbons annealed at for 1 h exhibit promising hard-magnetic properties at room temperature: ; and . Strong exchange coupling between hard and soft magnetic phases was demonstrated by a smooth demagnetizing curve and positive -peak in the Henkel plot. The magnetic properties measured from 5 to 750 K reveals that the hard characteristics remains rather stable up to 550 K, indicating a good prospect for the use of these permanent magnets in a wide temperature range.