The discovery of superconducting H₃S with a critical temperature T_c∼200 K opened a door to room temperature superconductivity and stimulated further extensive studies of hydrogen-rich compounds stabilized by high pressure. Here, we report a comprehensive study of the yttrium-hydrogen system with the highest predicted T_cs among binary compounds and discuss the contradictions between different theoretical calculations and experimental data. We synthesized yttrium hydrides with the compositions of YH₃, YH₄, YH₆ and YH₉ in a diamond anvil cell and studied their crystal structures, electrical and magnetic transport properties, and isotopic effects. We found superconductivity in the Im-3m YH₆ and P6₃/mmc YH₉ phases with maximal T_cs of ∼220 K at 183 GPa and ∼243 K at 201 GPa, respectively. Fm-3m YH₁₀ with the highest predicted T_c> 300 K was not observed in our experiments, and instead, YH₉ was found to be the hydrogen-richest yttrium hydride in the studied pressure and temperature range up to record 410 GPa and 2250 K.

Polymorphism, which describes the occurrence of different lattice structures in a crystalline material, is a critical phenomenon in materials science and condensed matter physics. Recently, configuration disorder was compositionally engineered into single lattices, leading to the discovery of high-entropy alloys and high-entropy oxides. For these novel entropy-stabilized forms of crystalline matter with extremely high structural stability, is polymorphism still possible? Here by employing in situ high-pressure synchrotron radiation X-ray diffraction, we reveal a polymorphic transition from face-centred-cubic (fcc) structure to hexagonal-close-packing (hcp) structure in the prototype CoCrFeMnNi high-entropy alloy. The transition is irreversible, and our in situ high-temperature synchrotron radiation X-ray diffraction experiments at different pressures of the retained hcp high-entropy alloy reveal that the fcc phase is a stable polymorph at high temperatures, while the hcp structure is more thermodynamically favourable at lower temperatures. As pressure is increased, the critical temperature for the hcp-to-fcc transformation also rises.

Encapsulating Earth's deep water filter: Small inclusions in diamonds brought up from the mantle provide valuable clues to the mineralogy and chemistry of parts of Earth that we cannot otherwise sample. Tschauner et al. found inclusions of the high-pressure form of water called ice-VII in diamonds sourced from between 410 and 660 km depth, the part of the mantle known as the transition zone. The transition zone is a region where the stable minerals have high water storage capacity. The inclusions suggest that local aqueous pockets form at the transition zone boundary owing to the release of chemically bound water as rock cycles in and out of this region. Science , this issue p. 1136

Hydrogen-rich superhydrides are believed to be very promising high-T_c superconductors. Recent experiments discovered superhydrides at very high pressures, e.g. FeH₅ at 130 GPa and LaH₁₀ at 170 GPa. With the motivation of discovering new hydrogen-rich high-T_c superconductors at lowest possible pressure, here we report the prediction and experimental synthesis of cerium superhydride CeH₉ at 80–100 GPa in the laser-heated diamond anvil cell coupled with synchrotron X-ray diffraction. Ab initio calculations were carried out to evaluate the detailed chemistry of the Ce-H system and to understand the structure, stability and superconductivity of CeH₉. CeH₉ crystallizes in a P6₃/mmc clathrate structure with a very dense 3-dimensional atomic hydrogen sublattice at 100 GPa. These findings shed a significant light on the search for superhydrides in close similarity with atomic hydrogen within a feasible pressure range. Discovery of superhydride CeH₉ provides a practical platform to further investigate and understand conventional superconductivity in hydrogen rich superhydrides.

The realization of a novel guest/host carbon-boron sp ³ framework opens the door for a new class of 3D carbon-based materials.

Formation of uranium polyhydrides UH _5–9 is predicted using the evolutionary algorithm USPEX and proved by high-pressure synthesis.