In the present comprehensive review we have specifically focused on polymer nanocomposites used as photocatalytic materials in fine organic reactions or in organic pollutants degradation. The selection of the polymer substrates for the immobilization of the active catalyst particles is motivated by several advantages displayed by them, such as: Environmental stability, chemical inertness and resistance to ultraviolet radiations, mechanical stability, low prices and ease availability. Additionally, the use of polymer nanocomposites as photocatalysts offers the possibility of a facile separation and reuse of the materials, eliminating thus the post-treatment separation processes and implicitly reducing the costs of the procedure. This review covers the polymer-based photocatalytic materials containing the most popular inorganic nanoparticles with good catalytic performance under UV or visible light, namely TiO₂, ZnO, CeO₂, or plasmonic (Ag, Au, Pt, Pd) NPs. The study is mainly targeted on the preparation, photocatalytic activity, strategies directed toward the increase of photocatalytic efficiency under visible light and reuse of the hybrid polymer catalysts.

One of the major issues faced when constructing various materials incorporating inorganic nanoparticles (NPs) is aggregation leading to loss of their final activity. In our work, cellulose acetate (CA) has been used to serve as matrix for the synthesis of UV-shielding and transparent films containing various amounts (1–5 wt.%) of cerium oxide (CeO₂) NPs. In order to attain an improved dispersion and a better connectivity between NPs and the cellulose matrix, the surface of CeO₂ NPs have been previously functionalized by the reaction with 3-aminopropyl(diethoxy)methylsilane (APDMS). The uniform dispersion of the NPs in the homogeneous thin films has been evidenced by using Transmission Electron Microscopy (TEM) and Fourier Transformation Infrared Spectroscopy (FTIR) characterization. The investigation of the optical properties for the hybrid films through UV-Vis spectroscopy revealed that the presence of CeO₂ NPs in the CA matrix determined the appearance of strong UV absorption bands in the region 312–317 nm, which supports their use as efficient UV absorbers. This study has shown that UV shielding ability of the nanocomposites can be easily tuned by adjusting the numberof inorganic NPs in the CA template.

Cerium oxide (CeO₂) nanoparticles were synthesized with a chemical precipitation method in different experimental conditions using cerium nitrate hexahydrate (Ce(NO₃)₃·6H₂O) as a precursor, modifying the solution pH, the reaction time, and Co atoms as dopants, in order to tune the band gap energy values of the prepared samples. The physical characteristics of the synthesized ceria nanoparticles were evaluated by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis analyses and photoluminescence measurements. XRD data revealed a pure cubic fluorite structure of CeO₂ NPs, the estimation of crystallite sizes by Scherrer’s formula indicates the formation of crystals with dimensions between 11.24 and 21.65 nm. All samples contain nearly spherical CeO₂ nanoparticles, as well as cubic, rhomboidal, triangular, or polyhedral nanoparticles that can be identified by TEM images. The optical investigation of CeO₂ samples revealed that the band gap energy values are between 3.18 eV and 2.85 eV, and, after doping with Co atoms, the E_g of samples decreased to about 2.0 eV. In this study, we managed to obtain CeO₂ NPs with E_g under 3.0 eV by only modifying the synthesis parameters. In addition, by doping with Co ions, the band gap energy value was lowered to 2.0 eV. This aspect leads to promising results that provide an encouraging approach for future photocatalytic investigations.

A facile method for the preparation of gold nanoparticles (AuNPs) with various morphologies, including triangles, cubes and nanospheres into a urethane methacrylate polymer matrix, has been developed. The hybrid nanocomposites have been obtained by photoreduction of a gold precursor in the presence of a 30 wt% urethane methacrylate containing quaternary ammonium structure and 70 wt% functional monomer, carboxyl oligo-urethane dimethacrylate. The final materials contain gold nanoparticles with a morphology dependant on the reaction conditions. The influence of photonic and chemical parameters on the shape of the nanoparticles has been examined. Specific interactions between the macromolecular network and the nascent particles play an important role insofar as they control the access of metal atoms to the different crystalline planes of the growing nanoparticles, which is necessary to obtain anisotropic objects. A common mechanism for the formation of the various types of AuNPs is proposed. Coupling the intrinsic characteristics of metal nanoparticles with those of the copolymer substrate could result in materials with innovative properties.