Cerium oxide (CeO₂) nanoparticles were synthesized with a chemical precipitation method in different experimental conditions using cerium nitrate hexahydrate (Ce(NO₃)₃·6H₂O) as a precursor, modifying the solution pH, the reaction time, and Co atoms as dopants, in order to tune the band gap energy values of the prepared samples. The physical characteristics of the synthesized ceria nanoparticles were evaluated by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis analyses and photoluminescence measurements. XRD data revealed a pure cubic fluorite structure of CeO₂ NPs, the estimation of crystallite sizes by Scherrer’s formula indicates the formation of crystals with dimensions between 11.24 and 21.65 nm. All samples contain nearly spherical CeO₂ nanoparticles, as well as cubic, rhomboidal, triangular, or polyhedral nanoparticles that can be identified by TEM images. The optical investigation of CeO₂ samples revealed that the band gap energy values are between 3.18 eV and 2.85 eV, and, after doping with Co atoms, the E_g of samples decreased to about 2.0 eV. In this study, we managed to obtain CeO₂ NPs with E_g under 3.0 eV by only modifying the synthesis parameters. In addition, by doping with Co ions, the band gap energy value was lowered to 2.0 eV. This aspect leads to promising results that provide an encouraging approach for future photocatalytic investigations.

Zinc oxide and zinc oxide doped with tin oxide (ZnO-SnO₂) particles were synthesized and successfully incorporated into a polymeric matrix by the photopolymerization reaction in the presence of Irg819 as the photoinitiator. The obtained samples were investigated by means of XRD, ESEM/EDX, TEM, FTIR, and Raman spectroscopy. The ZnO particles were obtained in the form of rods agglomerated in flower (or star) structures with lengths of 2–4 μm and widths between 30 and 100 nm, while ZnO-SnO₂ samples evolved in the form of cubes, with sides of 350 nm. The prepared composite films with ZnO and ZnO-SnO₂ particles were tested in the photocatalytic degradation of malachite green (MG) dye. While the ZnO-based composite film showed a fairly high photocatalytic activity, the hybrid film containing ZnO doped with SnO₂ displayed 100% photocatalytic activity after only 45 min of irradiation, being among the most efficient photocatalysts known for MG degradation. In addition, the recycling tests demonstrated that this film displayed high stability during the photocatalysis reaction since no decrease in the photocatalytic performance was noticed after the first three cycles, indicating its suitability for dyes removal and wastewater purification.

Hybrid polymeric materials, due to the unique combination of properties that can be obtained by the convenient variation of organic and inorganic components, represent an attractive alternative for many applications, especially photocatalysis. Herein, we report the preparation of nanocomposite films containing functionalized ZnO nanoparticles, as well as in situ photogenerated noble metal nanoparticles (Ag, Au, Pd), for the achieving of materials with enhanced photocatalytic activity under visible light. The flexible free-standing nanocomposite films were synthesized by photopolymerization of a monomer mixture (silane castor oil urethane dimethacrylate and polypropylene oxide urethane dimethacrylate) in the presence of a Irgacure 819 photoinitiator. The efficiency of ZnO NPs functionalization was established by Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis, while the polymer composites were characterized by UV-Vis spectroscopy, X-ray diffraction, transmission electron microscopy and scanning electron microscopy to evidence the formation, size and distribution of the nanoparticles inside the photocrosslinked matrix. To establish the photocatalytic capacity of nanocomposite films, the decomposition of various pollutants (methyl orange, phenol, metronidazole) was monitored under visible light irradiation, the best results being obtained for Au/ZnO film. Also, the advantage of immobilizing the catalysts in a polymeric support and its recycling ability without a significant decrease in photocatalytic efficiency was analysed.