The emissions of greenhouse gases, especially CO2, have been identified as the main contributor for global warming and climate change. Carbon capture and storage (CCS) is considered to be the most promising strategy to mitigate the anthropogenic CO2 emissions. This review aims to provide the latest developments of CO2 storage from the perspective of improving safety and economics. The mechanisms and strategies of CO2 storage, focusing on their characteristics and current status, are discussed firstly. In the second section, the strategies for assessing and ensuring the security of CO2 storage operations, including the risks assessment approach and monitoring technology associated with CO2 storage, are outlined. In addition, the engineering methods to accelerate CO2 dissolution and mineral carbonation for fixing the mobile CO2 are also compared within the second section. The third part focuses on the strategies for improving economics of CO2 storage operations, namely enhanced industrial production with CO2 storage to generate additional profit, and co-injection of CO2 with impurities to reduce the cost. Moreover, the role of multiple CCS technologies and their distribution on the mitigation of CO2 emissions in the future are summarized. This review demonstrates that CO2 storage in depleted oil and gas reservoirs could play an important role in reducing CO2 emission in the near future and CO2 storage in saline aquifers may make the biggest contribution due to its huge storage capacity. Comparing the various available strategies, CO2-enhanced oil recovery (CO2-EOR) operations are supposed to play the most important role for CO2 mitigation in the next few years, followed by CO2-enhanced gas recovery (CO2-EGR). The direct mineralization of flue gas by coal fly ash and the pH swing mineralization would be the most promising technology for the mineral sequestration of CO2. Furthermore, by accelerating the deployment of CCS projects on large scale, the government can also play its role in reducing the CO2 emissions.
Underground gas storage reservoirs (UGSRs) are used to keep the natural gas supply smooth. Native natural gas is commonly used as cushion gas to maintain the reservoir pressure and cannot be extracted in the depleted gas reservoir transformed UGSR, which leads to wasting huge amounts of this natural energy resource. CO2 is an alternative gas to avoid this particular issue. However, the mixing of CO2 and CH4 in the UGSR challenges the application of CO2 as cushion gas. In this work, the Donghae gas reservoir is used to investigate the suitability of using CO2 as cushion gas in depleted gas reservoir transformed UGSR. The impact of the geological and engineering parameters, including the CO2 fraction for cushion gas, reservoir temperature, reservoir permeability, residual water and production rate, on the reservoir pressure, gas mixing behavior, and CO2 production are analyzed detailly based on the 15 years cyclic gas injection and production. The results showed that the maximum accepted CO2 concentration for cushion gas is 9% under the condition of production and injection for 120 d and 180 d in a production cycle at a rate of 4.05 kg/s and 2.7 kg/s, respectively. The typical curve of the mixing zone thickness can be divided into four stages, which include the increasing stage, the smooth stage, the suddenly increasing stage, and the periodic change stage. In the periodic change stage, the mixed zone increases with the increasing of CO2 fraction, temperature, production rate, and the decreasing of permeability and water saturation. The CO2 fraction in cushion gas, reservoir permeability, and production rate have a significant effect on the breakthrough of CO2 in the production well, while the effect of water saturation and temperature is limited.
The meaningful utilization of artificially created multiple fractures in tight formations is associated with the performance behavior of such flow channels, especially in the case of thermal energy extraction from sedimentary geothermal system. In this study, an innovative idea is presented to develop a numerical model for geothermal energy production based on concrete physical performance of an artificially created tensile multi-fracture system in a simplified manner. The state-of-the-art software FLAC3Dplus-TOUGH2MP-TMVOC are integrated to develop a coupled thermo-hydro-mechanical (THM) fictive model for constructing a multi-fracture scheme and estimating heat extraction performance. By incorporating the actual fracture width of newly created subsequent fracture under the effect of stress shadow, cubic law is implemented for fluid flow and geothermal energy production. The results depict that fracture spacing plays a vital role in the energy contribution through multiple fractures. Afterwards, a field case study to design huge multiple hydraulic fractures was performed in the geothermal well GB X1 in North Germany. The attenuation of fracture propagation becomes more significant when massive multiple fracturing operation is performed especially in the case of lower fracture spacing. The fictive model results will be extended to study the geothermal utilization of the North German basin through massive multiple fractures in our future work.