In the course of increasing electric mobility, the effect of electricity on parts of machines is more significant than before. Rolling bearings and their lubrication, as a part of electric motors, are subjected to harmful currents, which lead to damage in the bearing in the long term. In order to avoid such damage, the influence of the lubricant in the bearing is becoming increasingly important. The electrical behaviour of the system can be investigated by analysing the discharge currents and the breakdown voltage in rolling bearings with lubricants of different compositions. This paper presents a procedure for characterizing the breakdown voltage at the rolling bearing and the influence of conductivity of the lubricants on harmful electrical phenomena.