Molybdenum disulfide and graphitic carbon nitride (MoS2-g-C3N4) nanocomposites with visible-light induced photocatalytic activity were successfully synthesized by a facile ultrasonic dispersion method. The crystalline structure and morphology of the MoS2-g-C3N4 nanocomposites were characterized by X-ray diffraction (XRD), transmission electron microcopy (TEM), high-resolution TEM (HRTEM) and scanning electron microscopy (SEM). The optical property of the as-prepared nanocomposites was studied by ultraviolet visible diffusion reflection (UV-vis) and photoluminescence(PL) spectrum. It could be observed from the TEM image that the MoS2 nanosheets and g-C3N4 nanoparticles were well combined together. Moreover, the photocatalytic activity of MoS2-g-C3N4 composites was evaluated by the removal of nitric oxide under visible light irradiation (>400nm). The experimental results demonstrated that the nanocomposites with the MoS2 content of 1.5 wt% exhibited optimal photocatalytic activity and the corresponding removal rate of NO achieved 51.67%, higher than that of pure g-C3N4 nanoparticles. A possible photocatalytic mechanism for the MoS2-g-C3N4 nanocomposites with enhanced photocatalytic activity could be ascribed to the hetero-structure of MoS2 and g-C3N4.
The flexible electrochromic supercapacitor electrode exhibits good electrochemical performances (13.6 mF cm−2, 138.2 F g−1) and high coloration efficiency (80.2 cm2 C−1).
Cu2O is one of the attractive photovoltaic materials for solar cells because of its low cost, nontoxicity, and good mobility. In this paper, an obvious enhancement of power conversion efficiency (PCE) for ZnO/Cu2O solar cells with perfectly oriented and micrometer grain sized Cu2O films was experimentally demonstrated. Cu2O was fabricated using radical oxidation of Cu foils at a low temperature of 500 °C. When followed by a rapid quenching and post annealing treatment, the perfectly oriented and micrometer sized Cu2O crystals (3∼4 μm) could be obtained. The crystal structure and optical properties of Cu2O were investigated in detail. Compared to conventional solar cells without any treatment, the PCE of the solar cells based on Cu2O with treatment was 3.18%, corresponding to a significant PCE improvement of 60.6%.
28 October 2019 in Journal of Materials Chemistry A
One-step anti-solvent deposition methods are widely applied in inverted perovskite solar cells (PSCs). However, anti-solvent processed films typically exhibit a small grain size and abundant defects. Herein, we propose a facile passivation approach using an ultrathin poly(triarylamine) (PTAA) layer to passivate the interfacial and grain boundary defects. An energy band alignment is realized by introducing an ultrathin PTAA layer sandwiched between the perovskite layer and the poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) layer to suppress interfacial recombination and accelerate hole transfer. By optimum design of the PTAA layer, we fabricate PSCs with a power conversion efficiency (PCE) of 19.04%, a fill factor (FF) of 82.59% and a short-circuit current density (Jsc) of 21.38 mA cm−2. To the best of our knowledge, the obtained FF value is the maximum among those reported for inverted chlorine-doped methyl perovskite solar cells (PSCs). After storage under ambient conditions for 10 days, the PCE of the PSCs with PTAA modification is still maintained at the 80% level, indicating substantially improved stability. Our work provides an effective method to boost PSCs with enhanced efficiency and stability.