Quantitative assessment of the impact of land use and climate change on hydrological processes is of great importance to water resources planning and management. The main objective of this study was to quantitatively assess the response of runoff to land use and climate change in the Zhengshui River Basin of Southern China, a heavily used agricultural basin. The Soil and Water Assessment Tool (SWAT) was used to simulate the river runoff for the Zhengshui River Basin. Specifically, a soil database was constructed based on field work and laboratory experiments as input data for the SWAT model. Following SWAT calibration, simulated results were compared with observed runoff data for the period 2006 to 2013. The Nash-Sutcliffe Efficiency Coefficient (NSE) and the correlation coefficient (R²) for the comparisons were greater than 0.80, indicating close agreement. The calibrated models were applied to simulate monthly runoff in 1990 and 2010 for four scenarios with different land use and climate conditions. Climate change played a dominant role affecting runoff of this basin, with climate change decreasing simulated runoff by −100.22% in 2010 compared to that of 1990, land use change increasing runoff in this basin by 0.20% and the combination of climate change and land use change decreasing runoff by 60.8m³/s. The decrease of forestland area and the corresponding increase of developed land and cultivated land area led to the small increase in runoff associated with land use change. The influence of precipitation on runoff was greater than temperature. The soil database used to model runoff with the SWAT model for the basin was constructed using a combination of field investigation and laboratory experiments, and simulations of runoff based on that new soil database more closely matched observations of runoff than simulations based on the generic Harmonized World Soil Database (HWSD). This study may provide an important reference to guide management decisions for this and similar watersheds.

Tungsten (W), a heavy metal with extensive industrial applications, has inadvertently been released into the environment yet received increasing attention regarding its potential toxicity to living organisms. In 2008, W was categorized as an emerging contaminant by the U.S. Environmental Protection Agency. Current research on its toxicity is fragmented, and the existing review papers and government reports, which primarily center on animal models, are often outdated. This review presents a comprehensive and systematic overview of the toxicity of W, particularly tungstate, to diverse biological entities including microorganisms, plants, animals, and humans. Notably, W holds biological significance in certain microorganisms but generally inhibits their growth and functions. High W exposure affects plant germination, growth, and nutrient absorption by disrupting transport and accumulation processes, and results in oxidative stress, root growth hindering, and vital enzyme disruption. In rodents, W accumulates in organs and is associated with tumor promotion, neurotoxicity, immunotoxicity, and reproductive implications. In humans, W exposure can compromise immune function, alter neurobehavioral patterns, and cause DNA damage, with potential carcinogenic effects, particularly in the lungs and bone marrow. This review consolidates recent toxicological findings and serves as a conceptual framework for future research on this emerging contaminant.

The accurate prediction of soil organic matter (SOM) content is essential for promoting sustainable soil management and addressing global climate change. Due to multiple factors such as topography and climate, especially in mountainous areas, SOM spatial prediction faces significant challenges. The main novelty of this study lies in proposing a geographic positional encoding mechanism that embeds geographic location information into the feature representation of a Transformer model. The encoder structure is further modified to enhance spatial awareness, resulting in the development of the Geo-Positional Transformer (GPTransformer). Furthermore, this model is integrated with a 1D-CNN to form a dual-branch neural network called the Geo-Positional Transformer-CNN (GPTransCNN). This study collected 1490 topsoil samples (0–20 cm) from cultivated land in Longshan County to develop a predictive model for mapping the spatial distribution of SOM across the entire cultivated area. Different models were comprehensively evaluated through ten-fold cross-validation, ablation experiments, and uncertainty analysis. The results show that GPTransCNN has the best performance, with an R² improvement of approximately 43% over the Transformer, 19% over the GPTransformer, and 15% over the 1D-CNN. This study demonstrates that by incorporating geographic positional information, GPTransCNN effectively combines the global modeling capabilities of the GPTransformer with the local feature extraction strengths of the 1D-CNN, which can improve the accuracy of SOM mapping in mountainous areas. This approach provides data support for sustainable soil management and decision-making in response to global climate change.