We employ spontaneous Brillouin light scattering spectroscopy and detailed theoretical calculations to reveal and identify elastic excitations inside the band gap of hypersonic hybrid superlattices. Surface and cavity modes, their strength and anticrossing are unambiguously documented and fully controlled by layer thickness, elasticity, and sequence design. This new soft matter based superlattice platform allows facile engineering of the density of states and opens new pathways to tunable phoxonic crystals.

Two new effective corrosion inhibitors, namely N-(n-octyl)-3-methylpyridinium bromide (Py8) and N-(n-dodecyl)-3-methylpyridinium bromide (Py12), have been presented. The cationic pyridinium-based surfactants were analyzed for the corrosion protection of general purpose steel (EN3B) against a strong corrosive media (3.5% NaCl, pH 1.5). The results of the electrochemical measurements, i.e., Tafel polarization, linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) revealed a mixed-type behavior of both inhibitors, and the maximum inhibition efficiency (IE) achieved with Py8 and Py12 was 85% and 82%, respectively. The process of adsorption of synthesized inhibitors followed the Langmuir adsorption isotherm, and a higher value of K_ads highlighted the existence of strong interaction between inhibitors and the EN3B mild steel surface. Furthermore, the values of ΔG°_ads were calculated to be −32 kJ mol⁻¹ for Py8 and −33 kJ mol⁻¹ for Py12, indicating the coexistence of both physisorbed and chemisorbed molecules. The surface morphology of EN3B mild steel samples was observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM), where the reduced surface roughness in the presence of Py8 and Py12 in chloride media further supported the evidence of an efficient inhibition process. Density functional theory (DFT) calculations reveal excellent correlation with the experimental results, with Py8 showing superior corrosion inhibition potential, signifying that the alkyl chain length and intramolecular charge transfer are crucial factors in deciding the inhibition performance of the synthesized cationic surfactants. Furthermore, this study proposes the mechanism for the adsorption of the surfactant-based inhibitors over the EN3B mild steel surface, which leads to the formation of an effective and protective anticorrosive film.

The growing usage of antibiotics and their subsequent release in water bodies have become a serious environmental concern. In this study, heterostructured photocatalysts C₃N₄/Nb₂O₅ have been synthesized using a simple hydrothermal method and applied to facilitate the degradation of the widely used antibiotic levofloxacin. The structural, morphological, and optical properties of the photocatalysts were characterized using XRD, SEM, TEM, UV–Vis and PL to establish the structure-property relationship. The type-II heterojunctions C₃N₄/Nb₂O₅ show remarkable activity under visible light irradiation, where Nb₂O₅ facilitates preferential adsorption of levofloxacin at the catalyst surface while C₃N₄ extends visible light absorption. This synergy resulted in superior catalytic performance (91%) in the optimized system, exceeding that of individual materials (Nb₂O₅ 30% and C₃N₄ 56%). The effect of catalyst dosage, pH, oxygen and point of zero is also investigated. The process is mainly photo-driven, and the trapping experiments reveal superoxide radicals as key species responsible for the degradation. Additionally, the adsorption behaviour, reformation of the degraded pollutant and reusability factors are evaluated to assess the practical feasibility of the photocatalytic system.

This research endeavor aimed to develop thin film blends of polypyrrole (PPy) and poly (styrene-isoprene-styrene) (SIS) with MoO₃ as a nanofiller for improved mechanical and electrical properties to widen its scope in the field of mechatronics. This study reports blends of polypyrrole (PPy) and poly (styrene-isoprene-styrene) (SIS) tri-block copolymer showing improved mechanical and electrical attributes while employing MoO₃ nanobelts as nanofillers that additionally improves the abovementioned properties in the ensuing nanocomposites. The synthesis of PPy/SIS blends and MoO₃/PPy/SIS nanocomposites was well corroborated with XRD, SEM, FTIR, and EDS analysis. Successful blending of PPy was yielded up to 15 w/w% PPy in SIS, as beyond this self-agglomeration of PPy was observed. The results showed a remarkable increase in the conductivity of insulating SIS copolymer from 1.5 × 10^−6.1 to 0.343 Scm⁻¹ and tensile strength up to 8.5 MPa with the 15 w/w% PPy/SIS blend. A further enhancement of the properties was recorded by embedding MoO₃ nanobelts with varying concentrations of the nanofillers into 15 w/w% PPy/SIS blends. The mechanical strength of the polymeric nanocomposites was enhanced up to 11.4 MPa with an increase in conductivity up to 1.51 Scm⁻¹ for 3 w/w% MoO₃/PPy-SIS blends. The resultant product exhibited good potential for electro-mechanical dual applications.