Ultra-thin magnetic dielectric films are of prime importance due to their applications for nanophotonics and spintronics. Here, we propose an efficient method for the magneto-optical investigation of ultra-thin magnetic films which allows one to access their state of magnetization and magneto-optical properties. It is based on the surface-plasmon-polariton-assisted transverse magneto-optical Kerr effect (TMOKE). In our experiments, sub-100 nm-thick bismuth-substituted lutetium iron-garnet films covered with a plasmonic gold grating have been analyzed. The excitation of surface plasmon-polaritons provides resonance enhancement of TMOKE up to 0.04 and makes it easily detectable in the experiment. For films thicker than 40 nm, the TMOKE marginally depends on the film thickness. A further decrease in the film thickness diminishes TMOKE since for such thicknesses the surface plasmon-polariton field partly penetrates inside the non-magnetic substrate. Nevertheless, the TMOKE remains measurable even for few-nm-thick films, which makes this technique unique for the magneto-optical study of ultra-thin films. Particularly, the proposed method reveals that the off-diagonal components of the magnetic film permittivity tensor grow slightly with the reduction of the film thickness.
The rapid development of industries discharges huge amounts of wastewater that contain surface water. For this reason, we used NiO/polydopamine (NiO/PDA) nanocomposite as an efficient material for the removal of Methyl violet 2B from water. It was synthesized and then characterized by Fourier Transform Infrared (FT-IR) spectroscopy, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX) analysis, Transmission Electron Microscopy (TEM), and Brunauer–Emmett–Teller (BET). The EDX analysis confirmed the presence of O, Ni, N, and C. The composite has an average particle size of 18 nm. Its surface area is 110.591 m2/g. It was found that the efficiency of dye removal by adsorption on NiO/PDA exceeded that of bare NiO. The adsorption capacity of NiO and NiO/PDA are 126 and 284 mg/g, respectively. The effects of adsorbent dose, dye concentration, and pH on the removal efficiency were examined. The efficiency increased with increasing the adsorbent dose and pH, but dropped from 85 to 73% within 30 min as the initial dye concentration was increased from 0.984 to 4.92 mg/L. Such a drop in the removal efficiency is due to the blocking of the surface-active sites of NiO/PDA, with the high population of dye molecules derived from the continuous increase in dye concentration. The adsorption results of the dye fitted well with the pseudo-second-order kinetics and Langmuir isotherm. The reusability data showed that NiO/PDA was stable across three adsorption–regeneration cycles, thus it can be considered a good recyclable and efficient adsorbent. Because of these results, it can be considered that this method can be applied for the treatment of wastewater.
As magnetized media by their nature have broken time reciprocity, the spatial symmetry of a material is also crucial and it imposes some restrictions on observed optical phenomena. Thus, for the normal incidence of light the spatial inversion symmetry makes transmitted and reflected light insensitive to the direction of the in-plane magnetization of the sample. To avoid this limitation, we propose here an approach based on a magnetoplasmonic structure with broken spatial symmetry. Combination of the specially designed spatial asymmetry with magnetism in the presence of optical losses provides a different effect, the transverse magnetophotonic transmittance effect, notable magnetooptical modulation of the optical transmittance at normal incidence enhanced by surface plasmon excitation. As the phenomenon is sensitive to asymmetry, it can serve as a powerful tool to study spin waves and currents in magnonic and optospintronic devices. The approach to marry the concepts of magnetoplasmonics and a lack of spatial symmetry is promising for the design of nanophotonics devices with outstanding properties.
Static laser scattering (SLS) is one of the most efficient techniques used for the molecular weight determination of polymer. Among of all polymers, polyvinyl alcohol (PVA) polymer was selected. A polystyrene (PS) was used as a standard polymer. A polyvinyl alcohol was investigated for its importance in pharmaceutical, biomedical, and industrial applications. Different concentrations in the range (3–9) × 10−3 g mL−1 were prepared. SLS data were obtained by using a self-built of the laser scattering system. The angular behavior of those selected polymer solutions with different concentrations were studied by plotting the intensity of the scattered light against the scattering angle in the range of 40–140°. By using Zimm plot the weight-average molecular weight Mw, radius of gyration RG, and second virial coefficient A2 of the standard PS and PVA were determined
Amorphous ferromagnetic microwires have drawn attention primarily due to their excellent soft magnetic properties as the elements of sensors. In this work, semi-hard magnetic microwires of composition Fe4.3Co67.7Si11B14Cr3 were obtained after a process of directional crystallization from amorphous state. The XRD analysis of crushed and whole wires identified the formation of the face-centered Co-modification as the main phase of directionally crystallized core alloy, which explains a large increase in anisotropy and coercivity. The application of a magnetic field during crystallization may orient the easy anisotropy axis of crystallites along the wire. This is confirmed by the investigation of crystallite orientation with respect to the wire axis and X-rays direction in diffractometer. The obtained results revealed that the formation of crystallites in amorphous Co-rich microwires occurs with the predominant orientation of the crystallographic direction [111] along the wire axis and the direction of a magnetic field during the directional crystallization process.