Controlling traps and structural defects in perovskite absorber layers is crucial for enhancing both the device efficiency and long-term stability of perovskite solar cells (PSCs). Here we demonstrate the modification of perovskite films by introducing low-cost green polymers, polysuccinimide (PSI) and polyasparagine (PASP), into the perovskite layer. Structural, morphological and optoelectronic properties of polymer-modified perovskite films were probed by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) and UV-Vis spectroscopy. The incorporation of PSI triggers interactions between the polymer and perovskite, leading to the passivation of surface defects at the grain boundaries and improved morphology of perovskite films. This defect passivation boosted PSC performance, providing power conversion efficiency (PCE) values up to 20.1%. An optimal polymer concentration of 0.1 mg/mL in the perovskite precursor solution was identified for an improvement in the photovoltaic performance. It was shown that the primary factor leading to the observed enhancement in the power conversion efficiency for PSI-modified PSCs is the increase in the lifetime of charge carriers due to the efficient passivation of surface defects and suppression of recombination losses. Additionally, PSI-modified PSCs demonstrated enhanced stability, retaining over 80% of their initial efficiency after 40 days of storage under ambient conditions without encapsulation. The obtained results highlight the effectiveness of green polymer additives in passivating surface defects in perovskite films and provide a viable approach for improving the stability and performance of perovskite solar cells.

We present the results of a comparative study on behaviour of the photovoltaic parameters in perovskite (PSC), dye-sensitized (DSC) and crystalline silicon ( c-Si) solar cells under various...

New types of two-terminal tandem solar cells DSC/ c-Si in which mesoscopic dye-sensitized solar cell (DSC) was connected in parallel with a crystalline silicon ( c-Si) solar cell, were developed and...

Here we introduce the research studies of perovskite solar cells with multistructured photoelectrodes based on very wide bandgap nanocrystalline materials. A series of solar cells with the device architecture FTO/c-TiO₂/ZrO₂(HfO₂)/CH₃NH₃PbI₃/Spiro-MeO-TAD/Au was fabricated and characterized. The results obtained demonstrate a successful possibility of PV application of the nanostructured oxide materials with bandgap values exceeding 5 eV. We propose a mechanism, which describes charge carrier transport at the interface of perovskite/multistructured photoelectrode.