A review of the investigations that have been made on adhesively bonded joints of fibre-reinforced plastic (FRP) composite structures (single skin and sandwich construction) is presented. The effects of surface preparation, joint configuration, adhesive properties, and environmental factors on the joint behaviour are described briefly for adhesively bonded FRP composite structures. The analytical and numerical methods of stress analysis required before failure prediction are discussed. The numerical approaches cover both linear and non-linear models. Several methods that have been used to predict failure in bonded joints are described. There is no general agreement about the method that should be used to predict failure since the failure strength and modes are different according to the various bonding methods and parameters, but progressive damage models are quite promising since important aspects of the joint behaviour can be modelled by using this approach. However, a lack of reliable failure criteria still exists, limiting in this way a more widespread application of adhesively bonded joints in principal load-bearing structural applications. An accurate strength prediction of the adhesively bonded joints is essential to decrease the amount of expensive testing at the design stage.

One parameter that influences the adhesively bonded joints performance is the adhesive layer thickness. Hence, its effect has to be investigated experimentally and should be taken into consideration in the design of adhesive joints. Most of the results from literature are for typical structural epoxy adhesives which are generally formulated to perform in thin sections. However, polyurethane adhesives are designed to perform in thicker sections and might have a different behavior as a function of adhesive thickness. In this study, the effect of adhesive thickness on the mechanical behavior of a structural polyurethane adhesive was investigated. The mode I fracture toughness of the adhesive was measured using double-cantilever beam (DCB) tests with various thicknesses of the adhesive layer ranging from 0.2 to 2 mm. In addition, single lap joints (SLJs) were fabricated and tested to assess the influence of adhesive thickness on the lap-shear strength of the adhesive. An increasing fracture toughness with increasing adhesive thickness was found. The lap-shear strength decreases as the adhesive layer gets thicker, but in contrast to joints with brittle adhesives the decrease trend was less pronounced.

The thermal stability of natural fiber composites is a relevant aspect to be considered since the processing temperature plays a critical role in the manufacturing process of composites. At higher temperatures, the natural fiber components (cellulose, hemicellulose, and lignin) start to degrade and their major properties (mechanical and thermal) change. Different methods are used in the literature to determine the thermal properties of natural fiber composites as well as to help to understand and determine their suitability for a certain applications (e.g., Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and differential mechanical thermal analysis (DMA)). Weight loss percentage, the degradation temperature, glass transition temperature (T_g), and viscoelastic properties (storage modulus, loss modulus, and the damping factor) are the most common thermal properties determined by these methods. This paper provides an overview of the recent advances made regarding the thermal properties of natural and hybrid fiber composites in thermoset and thermoplastic polymeric matrices. First, the main factors that affect the thermal properties of natural and hybrid fiber composites (fiber and matrix type, the presence of fillers, fiber content and orientation, the treatment of the fibers, and manufacturing process) are briefly presented. Further, the methods used to determine the thermal properties of natural and hybrid composites are discussed. It is concluded that thermal analysis can provide useful information for the development of new materials and the optimization of the selection process of these materials for new applications. It is crucial to ensure that the natural fibers used in the composites can withstand the heat required during the fabrication process and retain their characteristics in service.

Natural fiber reinforced polymer composites (NFRCs) have demonstrated great potential for many different applications in various industries due to their advantages compared to synthetic fiber-reinforced composites, such as low environmental impact and low cost. However, one of the drawbacks is that the NFRCs present relatively low mechanical properties and the absorption of humidity due to the hydrophilic characteristic of the natural fibre. One method to increase their performance is hybridization. Therefore, understanding the properties and potential of using multiple reinforcement’s materials to develop hybrid composites is of great interest. This paper provides an overview of the recent advances in hybrid natural fiber reinforced polymer composites. First, the main factors that affect the performance of hybrid fiber-reinforced composites were briefly discussed. The effect of hybridization on the mechanical and thermal properties of hybrid composites reinforced with several types of natural fibers (i.e., sisal, jute, curauá, ramie, banana, etc.) or natural fibers combined with synthetic fibers is presented. Finally, the water absorption behaviour of hybrid fiber-reinforced composites is also discussed. It was concluded that the main challenges that need to be addressed in order to increase the use of natural-natural or natural-synthetic hybrid composites in industry are the poor adhesion between natural fibers and matrix, thermal stability and moisture absorption of natural fibers. Some of these challenges were addressed by recent development in fibers treatment and modification, and product innovation (hybridization).