Devices known as electronic noses (ENs), electronic tongues (ETs), and electronic eyes (EEs) have been developed in recent years in the in situ study of real matrices with little or no manipulation of the sample at all. The final goal could be the evaluation of overall quality parameters such as sensory features, indicated by the “smell”, “taste”, and “color” of the sample under investigation or in the quantitative detection of analytes. The output of these sensing systems can be analyzed using multivariate data analysis strategies to relate specific patterns in the signals with the required information. In addition, using suitable data-fusion techniques, the combination of data collected from ETs, ENs, and EEs can provide more accurate information about the sample than any of the individual sensing devices. This review’s purpose is to collect recent advances in the development of combined ET, EN, and EE systems for assessing food quality, paying particular attention to the different data-fusion strategies applied.
1 August 2015 in Chemometrics and Intelligent Laboratory Systems
In the present work sparse-based methods are applied to the analysis of hyperspectral images with the aim at studying their capability of being adequate methods for variable selection in a classification framework. The key aspect of sparse methods is the possibility of performing variable selection by forcing the model coefficients related to irrelevant variables to zero. In particular, two different sparse classification approaches, i.e. sPCA+kNN and sPLS-DA, were compared with the corresponding classical methods (PCA + kNN and PLS-DA) to classify Arabica and Robusta coffee species. Green coffee samples were analyzed using near infrared hyperspectral imaging and the average spectra from each hyperspectral image were used to build training and test sets; furthermore a test image was used to evaluate the performances of the considered methods at pixel-level. In our case, sparse methods led to similar results as classical methods, with the advantage of obtaining more interpretable and parsimonious models. An important result to highlight is that variable selection performed with two different sparse classification approaches converged to the selection of same spectral regions, which implies the chemical relevance of those regions in the discrimination of Arabica and Robusta coffee species
Hyperspectral imaging allows to easily acquire tens of thousands of spectra for a single sample in few seconds; though valuable, this data-richness poses many problems due to the difficulty of handling a representative amount of samples altogether. For this reason, we recently proposed an approach based on the idea of reducing each image into a one-dimensional signal, named hyperspectrogram, which accounts both for spatial and for spectral information. In this manner, a dataset of hyperspectral images can be easily and quickly converted into a set of signals (2D data matrix), which in turn can be analyzed using classical chemometric techniques. In this work, the hyperspectrograms obtained from a dataset of 800 NIR-hyperspectral images of two different apple varieties were used to discriminate bruised from sound apples using iPLS-DA as variable selection algorithm, which allowed to efficiently detect the presence of bruises. Moreover, the reconstruction as images of the selected variables confirmed that the automated procedure led to the exact identification of the spatial features related to the onset and to the subsequent evolution with time of the bruise defect