In this work, recycled poly(ethylene terephthalate) (PETR) was blended with virgin high-density polyethylene (HDPE) in an internal mixer in an attempt to obtain a material with improved properties. A compatibilizer (PE-g-MA) and a chain extender (Joncryl) were added to the PETR/HDPE blend and the rheological and thermal properties of the modified and unmodified blends as well as those of virgin PET with virgin HDPE (PETV/HDPE). All the blends were characterized by torque rheometry, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The data obtained indicate that the incorporation of either the chain extender or the compatibilizer agent led to increases in torque (and hence in viscosity) of the blend compared to that of the neat polymers. The joint incorporation of the chain extender and compatibilizer further increased the viscosity of the systems. Their effect on the crystallinity parameters of HDPE was minimal, but they reduced the crystallinity and crystallization temperature of virgin and recycled PET in the blends. The thermal stability of the PETR/HDPE blend was similar to that of the PETV/HDPE blend, and it was not affected by the incorporation of the chain extender and/or compatibilizer.
The development of thermal energy storage systems is a possible solution in the search for reductions in the difference between the global energy supply and demand. In this context, the ability of some materials, the so-called phase change materials (PCMs), to absorb and release large amounts of energy under specific periods and operating conditions has been verified. The applications of these materials are limited due to their low thermal conductivity, and thus, it is necessary to associate them with high-conductivity materials, such as metals, to make the control of energy absorption and release times possible. Bearing this in mind, this paper presents a numerical analysis of the melting process of a PCM into a triplex tube heat exchanger (TTHX) with finned copper tubes, which allowed for the heat transfer between a heating fluid (water) and the phase change material to power a liquid-desiccant air conditioning system. Through the analysis of the temperature fields, liquid fractions, and velocities, as well as the phase transition, it was possible to describe the material charging process; then, the results were compared with experimental data, which are available in the specialized literature, and presented mean errors of less than 10%. The total required time to completely melt the PCM was about 105.5 min with the water being injected into the TTHX at a flow rate of 8.3 L/min and a temperature of 90 °C. It was observed that the latent energy that accumulated during the melting process was 1330 kJ, while the accumulated sensitive energy was 835 kJ. The average heat flux at the internal surface of the inner tube was about 3 times higher than the average heat flux at the outer surface of the TTHX intermediate tube due to the velocity gradients that developed in the internal part of the heat exchanger, and was about 10 times more intense than those observed in the external region of the equipment.
Drying and firing of ceramic products are processes that require high energy consumption. Making these processes more efficient can improve product quality, reduce processing time and energy consumption, and promote economic and environmental gains. In this sense, this work aims to quantify heat transfer in an intermittent ceramic kiln during the heating and cooling stages, with and without thermal insulation. All mathematical formulation is based on the first law of thermodynamics. From the results, we conclude that the greatest heat loss occurs by radiation in the sidewalls of the equipment, and that a considerable amount of energy is required to heat the sidewalls, base, and ceiling of the kiln. Further, with the use of thermal insulation, it was concluded that a high reduction in the heat lost through the sidewalls was achieved, thus providing a global energy gain of approximately 35% and a reduction in the maximum external surface temperature from 249.34 to 79.47 °C when compared to the kiln without thermal insulation, reducing the risks of work accidents and thermal discomfort when in operation.
In the oil industry and academy, the treatment of water contaminated with oil using conventional hydrocyclones and membranes has been an alternative to meet the requirements established by environmental control agencies. However, such equipment is not fully efficient in the treatment of much diluted oily water, with both presenting restrictions in their performance. In this sense, the present work proposes to study the separation process of oily water using a new configuration of hydrocyclone, equipped with a porous ceramic membrane in the conical part’s wall (filtering hydrocyclone). For the theoretical study, a Eulerian–Eulerian approach was applied to solve the mass and momentum conservation equations, and the turbulence model, using the computational fluid dynamics technique. The results of the velocity, pressure and volumetric fraction of the involved phases, and the separation performance of the hydrocyclone, are presented, analyzed, and compared with those obtained with a conventional hydrocyclone. The results confirmed the high potential of the proposed equipment to be used in the separation of the water and oil mixture.
Smoke is the main threat of death in fires. For this reason, it becomes extremely important to understand the dispersion of this pollutant and to verify the influence of different control systems on its spread through buildings, in order to avoid or minimize its effects on living beings. Thus, this work aims to perform thermo-fluid dynamic study of smoke dispersion in a closed environment. All numerical analysis was performed using the Fire Dynamics Simulator (FDS) software. Different simulations were carried out to evaluate the influence of the exhaust system (natural or mechanical), the heat release rate (HRR), ventilation and the smoke curtain in the pollutant dispersion. Results of the smoke layer interface height, temperature profile, average exhaust volumetric flow rate, pressure and velocity distribution are presented and discussed. The results indicate that an increase in the natural exhaust area increases the smoke layer interface height, only for the well-ventilated compartment (open windows); an increase in the HRR accelerates the downward vertical displacement of the smoke layer and that the 3 m smoke curtain is efficient in exhausting smoke, only in the case of poorly ventilated compartments (i.e., with closed windows).
Wastewater from the oil industry can be considered a dangerous contaminant for the environment and needs to be treated before disposal or re-use. Currently, membrane separation is one of the most used technologies for the treatment of produced water. Therefore, the present work aims to study the process of separating oily water in a module equipped with a ceramic membrane, based on the Eulerian–Eulerian approach and the Shear-Stress Transport (SST k-ω) turbulence model, using the Ansys Fluent® 15.0. The hydrodynamic behavior of the water/oil mixture in the filtration module was evaluated under different conditions of the mass flow rate of the fluid mixture and oil concentration at the entrance, the diameter of the oil particles, and membrane permeability and porosity. It was found that an increase in the feed mass flow rate from 0.5 to 1.5 kg/s significantly influenced transmembrane pressure, that varied from 33.00 to 221.32 kPa. Besides, it was observed that the particle diameter and porosity of the membranes did not influence the performance of the filtration module; it was also verified that increasing the permeability of the membranes, from 3 × 10−15 to 3 × 10−13 m2, caused transmembrane pressure reduction of 22.77%. The greater the average oil concentration at the permeate (from 0.021 to 0.037 kg/m3) and concentrate (from 1.00 to 1.154 kg/m3) outlets, the higher the average flow rate of oil at the permeate outlets. These results showed that the filter separator has good potential for water/oil separation.