Our research aim is to develop a new composite material via electrospinning and dip coating methodology. Among bioabsorbable polymers, Polylactic acid (PLA) is viewed as a suitable base material for biomedical usages such as drug delivery and wound dressing. Additionally, these bioabsorbable materials can be used for filtration applications in terms of antibacterial activity the integration of hexadecyl trimethyl ammonium chloride-modified montmorillonite (CTAC-MMT) into PLA fibers would improve mechanical and absorption properties of the PLA fibers. This research aimed to investigated a new method of combining electrospun PLA with dip coating of CTAC-MMT solution. Precisely, electrospun PLA nanofibers were treated with methanol and dipped in a CTAC-MMT suspension. The resultant layer composite of PLA nanofibers and CTAC-MMT was then characterized by elemental analysis. For material characterization and morphological structure analysis, we performed FTIR, SEM-EDS, XPS, DSC, and X-ray diffraction. Through mechanical testing and contact angle measurements, it was found that CTAC-MMT shows a slight improvement in mechanical and absorption properties. Results of characterization techniques have shown that CTAC-MMT can be used as a good filler for composites processed through the dip-coating method. Moreover, results also showed that the diameter of microfibers is affected by concentrations of PLA.