Bearing steel (GCr15) is widely used in key parts of mechanical transmission for its excellent mechanical properties. Electrochemical machining (ECM) is a potential method for machining GCr15, as the machining process is the electrochemical dissolution of GCr15 regardless of its high hardness (>50 HRC). In ECM, NaNO3 solution is a popular electrolyte, as it has the ability to help in the nonlinear dissolution of many metallic alloy materials, making it useful for precision machining. However, due to high carbon content of GCr15, the electrochemical dissolution of GCr15 is unique, and there is always a black layer with high roughness on the machined surface, reducing the surface quality. In order to improve the electrochemical machining of GCr15 with a high surface quality, the surface characteristics of GCr15 in ECM were investigated. The anodic polarisation curve in the NaNO3 electrolyte was measured and electrochemical dissolution experiments were conducted with different current densities. SEM, XRD, and XPS were employed to analyse the surface morphology and composition formed on the machined surface at different current densities. The initial results showed that there were two parts (black part and bright part) formed on the machined surface when a short circuit occurred, and the test results suggested that the black part contained a mass of Fe3O4 while the bright part was composed of mainly Fe and Fe3C. Further investigation uncovered that a black flocculent layer (Fe3O4) always formed in a low current density (32 A/cm2) with high roughness. With the current density increased, the amount of black flocculent layer was reduced, and Fe3C particles appeared on the machined surface. When the current density reached 81 A/cm2, the entire flocculent oxide layer was removed, only some spherical Fe3C particles were inserted on the machined surface, and the roughness was reduced from Ra7.743 μm to Ra1.783 μm. In addition, due to exposed Fe3C particles on the machined surface, the corrosion resistance of the machined surface was significantly improved. Finally, circular arc grooves of high quality were well manufactured with current density of 81 A/cm2 in NaNO3 electrolyte.
At present, there are some challenging issues for diamond electroplating devices, such as poor particle–cathode contact uniformity, low conductivity, inefficient deposition, and complex disassembly/cleaning process of the device. To overcome these issues, an ultrasonic oscillation-assisted nickel electroplating device is innovatively designed and presented in this paper. The device features: (1) innovative architecture enabling rapid disassembly; (2) ultrasonic enhancement of diamond particle mobility (frequency × amplitude); (3) optimized electrical contact interfaces. In this paper, the effects of electroplating current, output power of ultrasonic oscillator and diamond particle size on nickel electroplating onto diamond surface are further studied particularly by ultrasonic assisted electroplating. The experimental results show that the ultrasonic oscillation assisted electroplating greatly improves the uniformity of the coating on the diamond surface and effectively prevents the adhesion between diamond particles. While the process parameters are electroplating current of 3 A, output power of ultrasonic oscillator 900 W, diamond particle size of 120/140, the weight-gain rate is 20.6%, the nickel content of the coating reaches 81.95%, and the coating is excellent uniformed without agglomeration. The research presented provides fundamental understanding for further development and application of ultrasonic oscillation-assisted electroplating technology particularly for broad precision engineering purposes.
As one of the most promising new materials in the field of materials science, high-entropy alloys (HEAs) have attracted widespread attention due to the unique structure, exceptional properties and engineering performance, and complex composition. The CoCrFeNiZr0.5 eutectic high-entropy alloys (EHEAs) exhibits excellent high-temperature thermal stability, ductility, creep resistance, and corrosion resistance, demonstrating great potential for applications in marine equipment. This paper explores the engineering feasibility of electrical discharge machining (EDM) of CoCrFeNiZr0.5 EHEAs and investigates the EDM of micro-holes using a hollow copper electrode on a CNC EDM drilling machine under various machining parameters, including different gap voltage, pulse-on time, pulse-off time, and pulse amplifier settings. The effects of these parameters on the inlet diameter, outlet diameter, and recast layer of the micro holes are analyzed. The optimal micro-hole machining parameters are determined by comprehensively considering machining efficiency and electrode wear: gap voltage of 33 V, pulse-on time of 3 μs, pulse-off time of 1 μs, and pulse amplifier output of 3 A. Adopting the parameters to process a button ingot sample with a depth of 5 mm, it was found that the machining speed is 7.79 mm/min and the electrode wear is 1 cm. This research renders the foundation for further development and engineering application of CoCrFeNiZr0.5 EHEAs in the context of high-value material design and manufacturing.
Coating diamond particle surfaces with a layer of high-temperature resistant nickel, which possesses weldability, effectively enhances the bonding strength between diamond particles and substrates in pre-grinding tools. This improves their stability and strength at high temperatures, thereby enhancing the performance, lifespan, and efficiency of grinding tools. This paper explores the electroless nickel plating process on diamond surfaces, analyzes the working principle of electroless nickel plating on diamond surfaces, and proposes the use of 2 g/L AgNO3 solution and 2 g/L AgNO3 + 10 mL/L NH3·H2O solution as Pd-free activating solutions. Experimental studies have demonstrated the feasibility of using silver nitrate as an activator, and it has been found that the 2 g/L AgNO3 + 10 mL/L NH3·H2O solution achieves a higher surface plating ratio when used as an activator for electroless nickel plating on diamond surfaces. Based on this, through orthogonal and single-factor experimental methods, the effects of ammonia solution concentration, sodium hypophosphite concentration, plating temperature, and diamond particle size on electroless nickel plating on diamond surfaces were investigated. The optimal process for electroless nickel plating on diamond surfaces was obtained: ammonia solution concentration of 17.5 mL/L, sodium hypophosphite concentration of 33 g/L, and plating temperature of 80 °C. Under this process, using diamond particles with a size of 120/140 for electroless nickel plating, a surface plating ratio of 10.75% electroless nickel-plated diamond can be achieved.
1 May 2023 in Journal of Physics: Conference Series
In electrolytic processing, the flow field of the electrolyte, the applied voltage, and the magnetic effect of the current itself have a significant effect on the stability, efficiency, and surface quality of the process. In this paper, the effects of different inlet pressures on the flow rate and different treatment voltages on the current density and magnetic induction strength are investigated by coupling several fields, such as flow, electric and magnetic fields, using COMSOL software. The simulation results show that the flow rate increases with the increase of inlet pressure, and the flow rate increases by 1 m/s for every 0.1 MPa. The current density increases with the increase of processing voltage, but its uniformity decreases, and the magnetic effect of the current itself also influences the magnitude of the current density