Beyond fundamental aspects of crystal growth and morphology, the growth of minerals is a challenging subject because in most cases we face a problem with unknown growth conditions. Actually, in the field of geological studies, we have to decipher the growth conditions of a crystal using the information contained in the very crystal. One of these characteristics of crystals that contain information about their growth is their morphology and time evolution. In this article, we introduce the subject of crystal morphology by using three important minerals, calcite, halite and gypsum, as three didactic case studies to illustrate the application of the current knowledge in the field
Contains 4 figures.Exploration in the Naica mine (Chihuahua, Mexico) recently unveiled several caves containing giant, faceted, and transparent\ud single crystals of gypsum (CaSO4•2H2O) as long as 11 m. These large crystals form at very low supersaturation. The problem is to explain how proper geochemical conditions can be sustained for a long time without large fluctuations that would trigger substantial nucleation. Fluid inclusion analyses show that the crystals grew from low-salinity solutions at a temperature of ~54 °C, slightly below the one at which\ud the solubility of anhydrite equals that of gypsum. Sulfur and oxygen isotopic compositions of gypsum crystals are compatible with growth from solutions resulting from dissolution of anhydrite previously precipitated during late hydrothermal mineralization, suggesting that\ud these megacrystals formed by a self-feeding mechanism driven by a solution-mediated, anhydrite-gypsum phase transition. Nucleation kinetics calculations based on laboratory data show that this mechanism\ud can account for the formation of these giant crystals, yet only when operating within the very narrow range of temperature identified by our fluid inclusion study. These singular conditions create a\ud mineral wonderland, a site of scientific interest, and an extraordinary\ud phenomenon worthy of preservation.We gratefully acknowledge Compañía Peñoles for the facilities provided during the field studies performed in the Naica mine, and the Ministerio de Educación y Ciencia of Spain for financial support.Peer reviewe
23 July 2001 in Acta Crystallographica Section D Structural Biology