In this study, the criterion for validity of the nighttime ozone chemical equilibrium assumption in the mesopause region is applied to Sounding of the Atmosphere using Broadband Emission Radiometry data for the year 2004 to define the boundary of this equilibrium. We demonstrate that the boundary varies within the range of 77–86 km depending on season and latitude and the retrieval of atomic oxygen from the equilibrium assumption below this boundary leads to significant (up to 5–8 times) underestimation of this component's concentration in the range of 80–85 km. However, this fact does not influence the subsequent atomic hydrogen retrieval.

In this work, we compare the values of 15 convective indices obtained from radiosonde and microwave temperature and water vapor profiles simultaneously measured over Nizhny Novgorod (56.2°N, 44°E) during 5 convective seasons of 2014–2018. A good or moderate correlation (with coefficients of ~0.7–0.85) is found for most indices. We assess the thunderstorm prediction skills with a lead time of 12 h for each radiosonde and microwave index. It is revealed that the effectiveness of thunderstorm prediction by microwave indices is much better than by radiosonde ones. Moreover, a good correlation between radiosonde and microwave values of a certain index does not necessarily correspond to similar prediction skills. Eight indices (Showalter Index, Maximum Unstable Convective Available Potential Energy (CAPE), Total Totals index, TQ index, Jefferson Index, S index, K index, and Thompson index) are regarded to be the best predictors from both the true skill statistics (TSS) maximum and Heidke skill score (HSS) maximum points of view. In the case of radiosonde data, the best indices are the Jefferson Index, K index, S index, and Thompson index. Only TSS and HSS maxima for these indices are close to the microwave ones, whereas the prediction skills of other radiosonde indices are essentially worse than in the case of microwave data. The analysis suggests that the main possible reason of this discrepancy is an unexpectedly low quality of radiosonde data.

For the retrieval of atomic oxygen via ozone observations in the extended mesopause region under sunlight conditions, two assumptions are used: first, the photochemical equilibrium of ozone and, second, that the ozone losses are dominated by ozone's dissociation from solar UV radiation, silently ignoring the O₃ destruction by atomic hydrogen. We verify both by 3-D modeling. We found that ozone approaches photochemical equilibrium at 75–100 km for daytime conditions. Hence, the first assumption is valid. However, the reaction of ozone with atomic hydrogen was found to be an important loss process and should not be omitted in retrieving atomic oxygen.