The use of superhydrophobic materials to remove particulate pollutants such as microplastics is still in its infancy. In a previous study, we investigated the effectiveness of three different types of superhydrophobic materials - coatings, powdered materials, and meshes - for removing microplastics. In this study, we will explain the removal process by considering microplastics as colloids and taking into account their wetting properties as well as those of a superhydrophobic surface. The process will be explained through the interactions of electrostatic forces, van der Waals forces, and the DLVO theory. In order to replicate and verify the previous experimental findings on the removal of microplastics using superhydrophobic surfaces, we have modified non-woven cotton fabrics with polydimethylsiloxane. We then proceeded to remove high-density polyethylene and polypropylene microplastics from water by introducing oil at the microplastics-water interface, and we determined the removal efficiency of the modified cotton fabrics. After achieving a superhydrophobic non-woven cotton fabric (159 ± 1°), we confirmed its effectiveness in removing high-density polyethylene and polypropylene microplastics from water with a removal efficiency of 99%. Our findings suggest that the binding energy of microplastics increases and the Hamaker constant becomes positive when they are present in oil instead of water, leading to their aggregation. As a result, electrostatic interactions become negligible in the organic phase, and van der Waals interactions become more important. The use of the DLVO theory allowed us to confirm that solid pollutants can be easily removed from the oil using superhydrophobic materials.

Microplastics are a global issue that affects the environment, economy, as well as human health. Herein, we present a superhydrophobic 304 stainless steel mesh obtained by chemical etching followed by a liquid-phase deposition of lauric acid that can be used for microplastic removal. Field emission scanning electron microscopy (FE-SEM) and high-resolution X-ray photoelectron spectroscopy (HR-XPS), among other techniques, were used to identify the hierarchical structure and chemical composition of the surface. They revealed that iron laurate decreased the surface free energy. The 304 stainless steel mesh was superhydrophobic (169°) and superoleophilic (0°). Taking advantage of these wetting properties, we showed an innovative use of these superhydrophobic surfaces in the removal of microplastics. Additionally, we analyzed the removal efficiency from a surface and colloidal point of view that allowed us to explain and clarify why microplastics can also be removed by their wetting properties. The loss of a double electrostatic cloud between the microplastics and the predominance of van der Waals interactions in the organic phase promote the removal of these persistent pollutants from water.