MoAlB is a potential candidate for high-temperature application since a dense, adherent alumina scale is formed. While, based on X-ray diffraction investigations, the formation of phase pure orthorhombic MoAlB coatings is observed, energy dispersive X-ray spectroscopy carried out in a scanning transmission electron microscope reveals the presence of Al-rich and O-rich regions within the MoAlB matrix. The oxidation kinetics of coatings and bulk is similar to the scale thickness formed on the MoAlB coating after oxidation at 1200 °C for 30 min is similar to the one extrapolated for bulk MoAlB. Furthermore, the oxidation kinetics of MoAlB coatings is significantly lower than the one reported for bulk Ti₂AlC. Finally, the elastic properties measured for the as-deposited coatings are consistent ab initio predictions.

We investigated the elastic properties of the HfV₂O₇ high-temperature phase, exhibiting negative thermal expansion, in a synergetic strategy of first-principle calculations and nanoindentation experiments performed on sputtered films. Self-consistent results were obtained for the measured elastic modulus (73 ± 14 GPa) and dispersion-corrected density functional theory calculations. The elastic properties of HfV₂O₇ are affected by long-range dispersion interaction, which may be induced by severe modification in the second-nearest neighbor O-O bond distance as obtained upon compression. HfV₂O₇ is composed of HfO₆, VO₄, and V₂O₇ building blocks, whereby the latter is characterized by an increasing V-O(-V) bond length upon compression.