Esther Molero

Dr. Esther Molero


Research Focus & Metrics

Academic Career Length

8Years (2019-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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6 April 2020 in Polymers
Verified
Journal Article
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EMEsther Molero
Esther Molero
JFJuan Jesús Fernández
Juan Jesús Fernández
OAOscar Rodriguez Alabanda
Oscar Rodriguez Alabanda
GGGuillermo Guerrero-Vacas
Guillermo Guerrero-Vacas
Pablo Eduardo RomeroPablo Eduardo Romero
Pablo Eduardo Romero
In the present work, ten data mining algorithms have been used to generate models capable of predicting the surface roughness of parts printed on polylactic acid (PLA) by using fused deposition modeling (FDM). The models have been trained using experimental data measured on 27 horizontal (XY) and 27 vertical (XZ) specimens, printed using different values for the parameters studied (layer height, extrusion temperature, print speed, print acceleration and flow). The models generated by multilayer perceptron (MLP) and logistic model trees (LMT) have obtained the best results in a cross-validation. Although it does not obtain such optimal results, the J48 algorithm (C4.5) allows the generation of models in the form of a decision tree. These trees permit to determine which print parameters have an influence on the surface roughness. For XY specimens, the surface roughness measured in the direction parallel to the extrusion path (Ra,0,XY ) depends on the flow, the print temperature and the layer height; in the direction perpendicular to the extrusion path, the surface roughness (Ra,90,XY) depends only on the flow. For XZ specimens, the surface roughness measured in the direction parallel to the extrusion path (Ra,0,XZ) depends only on the print speed; in the direction perpendicular to the extrusion path (Ra,90,XZ), it depends on the layer height and the extrusion temperature. According to the study carried out, the most suitable set up provides values of Ra,0,XY, Ra,90,XY, Ra,0,XZ and Ra,90,XZ equal to 0.46, 1.18, 0.45 and 11.54, respectively. A practical application of this work is the manufacture of PLA frame glasses using FDM.

24 October 2019 in Polymers
Verified
Journal Article
Open access
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GGGuillermo Guerrero-Vacas
Guillermo Guerrero-Vacas
OAOscar Rodriguez Alabanda
Oscar Rodriguez Alabanda
Pablo Eduardo RomeroPablo Eduardo Romero
Pablo Eduardo Romero
CSCarlos Soriano
Carlos Soriano
EMEsther Molero
Esther Molero
JLJON LAMBARRI
JON LAMBARRI
Fluoropolymers such as PFA are used as coatings for the protection of metal substrates due to their high chemical inertia and non-stick properties. These are “wear and tear” coatings and they degrade, at which point they should be removed for a new application. The removal of these types of coating by laser is of interest due to the process’s flexibility, precision, ease of automation, and environmental sustainability. The efficiency of the procedure was shown with the use of a source in a pulsed Nd:YAG and a source in continuous mode of fiber (Yb). The rates of stripping (cm2/min) and fluence (J/cm2) were analyzed and related to the power of the laser sources. Variations of the substrate after stripping were studied: roughness and hardness. The properties of the coating, thickness, roughness, water sliding angle, and microhardness were also evaluated. It was concluded that the laser in continuous mode was more efficient than the pulsed laser; laser removal of fluoropolymers has a strong relationship with reflectivity, and the mechanical and surface properties of the substrate after stripping remained virtually unchanged.

10 February 2020 in Materials
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Journal Article
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GGGuillermo Guerrero-Vacas
Guillermo Guerrero-Vacas
DCDavid Carrizo-Tejero
David Carrizo-Tejero
OAOscar Rodriguez Alabanda
Oscar Rodriguez Alabanda
Pablo Eduardo RomeroPablo Eduardo Romero
Pablo Eduardo Romero
EMEsther Molero
Esther Molero
Polytetrafluoroethylene (PTFE) coatings are used in many applications and processing industries. With their use, they wear out and lose properties and must be replaced by new ones if the cost of the element so advises. There are different stripping techniques, but almost all of them are very difficult and require strict environmental controls. It is a challenge to approach the process through efficient and more sustainable techniques. In the present work, we have studied the stripping of PTFE coatings by projection with abrasives (1 step) as an alternative to carbonization + sandblasting procedures (2 steps). For this purpose, different types of abrasives have been selected: brown corundum, white corundum, glass microspheres, plastic particles, and a walnut shell. The tests were performed at pressures from 0.4 to 0.6 MPa on PTFE-coated aluminium substrates of EN AW-5182 H111 alloy. Stripping rates, surface roughness, and substrate hardness have been studied. Scanning electron microscopy (SEM) images of sandblasted specimens have also been obtained. All abrasives improved mechanical and surface properties in one-step vs. two-step processes. The abrasives of plastic and glass microspheres are the most appropriate for the one-step process, which increases the hardness and roughness level Ra in the substrate. Corundum abrasives enable the highest stripping rates.

19 September 2019 in Metals
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Journal Article
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OAOscar Rodriguez Alabanda
Oscar Rodriguez Alabanda
Pablo Eduardo RomeroPablo Eduardo Romero
Pablo Eduardo Romero
EMEsther Molero
Esther Molero
GGGuillermo Guerrero-Vacas
Guillermo Guerrero-Vacas
For the wiredrawing of aluminium, the initial wire rod is obtained by continuous inverted casting. The raw geometry is industrially processed in a linear multi-step wiredrawing sequence to obtain a wire that is commonly used for the manufacture of electrical conductors. In the present work a complete study of the material has been made. The experimental procedure consisted in the realization of a sequence of section reduction stages in the laboratory, a sequence designed following the technological criteria recommended by the manufacturer of the drawing machine in which the industrial process will be implemented. From the specimens corresponding to each reduction step, it has been possible to know the evolution of the main mechanical properties when this pure aluminium is processed by wiredrawing. This information has led to establish the hardening law by which it is possible characterize the plastic behaviour of this pure metal when it is transformed by this specific sequential process of cold forming. The strain hardening law has been implemented in a numerical simulation software application and the experimental setup has been simulated for its validation. Finally, the classic analytical solution founded in the “slab method” has been applied for the design of a proposal for the optimization of the industrial wiredrawing process.

19 October 2024 in Polymers
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Journal Article
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JMJosé A. Martínez-Sánchez
José A. Martínez-Sánchez
Pablo Eduardo RomeroPablo Eduardo Romero
Pablo Eduardo Romero
FCFrancisco Comino
Francisco Comino
EMEsther Molero
Esther Molero
Manuel Ruiz de AdanaManuel Ruiz de Adana
Manuel Ruiz de Adana
This study aims to optimise the water vapour adsorption capacity of polylactic acid (PLA) and wood composite materials for application in dehumidification systems through material extrusion additive manufacturing. By analysing key process parameters, including nozzle diameter, layer height, and temperature, the research evaluates their impact on the porosity and adsorption performance of the composite. Additionally, the influence of different infill densities on moisture absorption is investigated. The results show that increasing wood content significantly enhances water vapour adsorption, with nozzle diameter and layer height identified as the most critical factors. These findings confirm that composite materials, especially those with higher wood content and optimised printing parameters, offer promising solutions for improving dehumidification efficiency. Potential applications include heating, ventilation, and air conditioning systems or environmental control. This work introduces an innovative approach to using composite materials in desiccant-based dehumidification and provides a solid foundation for future research. Further studies could focus on optimising material formulations and scaling this approach for broader industrial applications.

20 November 2019 in Coatings
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Journal Article
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GGGuillermo Guerrero-Vacas
Guillermo Guerrero-Vacas
Miguel Ángel Rodríguez-ValverdeMiguel Ángel Rodríguez-Valverde
Miguel Ángel Rodríguez-Valverde
PCPedro Castilla-Montilla
Pedro Castilla-Montilla
FAFrancisco Alguacil-Salamanca
Francisco Alguacil-Salamanca
OAOscar Rodriguez Alabanda
Oscar Rodriguez Alabanda
FRFrancisco Javier Montes Montes Ruiz-cabello
Francisco Javier Montes Montes Ruiz-cabello
Aluminum-magnesium (Al-Mg) alloy and aluminum-coated steel (aluminized steel) are typically used for the manufacturing of baking trays and molds. For these applications, these materials must be modified to develop release and hydrophobic properties. With this aim, the bare substrates are typically coated with low-surface energy materials such as fluoropolymers, elastomers, or sol-gel layers. In this work, some alternative strategies to prepare these functional surfaces are presented. We used three-step processes involving (i) micro-texturing, (ii) nano layer deposition through immersion and electrodeposition, and (iii) hydrophobization. The raw substrates were sanded or sandblasted at the micro scale, accordingly. Texturization at the nano scale was achieved with a cerium layer formed by electrodeposition or solution immersion. The cerium layers were hydrophobized with fatty acids. The wetting properties of the samples were studied with tilting-plate and bouncing drop methods. We measured the surface roughness of the samples by contact profiling and analyzed their surface morphology using a field emission scanning electron microscope (FESEM). The elemental chemical composition of the samples was analyzed by energy-dispersive X-ray spectroscopy (EDX). The wettability results indicated that the best performance for the Al-Mg substrates was reached by sandblasting and later immersion in a cerium nitrate solution. For aluminized steel substrates, the best results were obtained with both electrodeposition and immersion methods using a cerium chloride solution.