Post-treatment is crucial to improve the comprehensive performance of laser-cladded martensitic stainless steel coatings. In this work, a low-temperature tempering treatment (210 °C), for the first time, was performed on the laser-cladded AISI 420 martensitic stainless steel coating. The microstructure and properties of the pre- and post-tempering specimens were carefully investigated by XRD, SEM, TEM, a micro-hardness tester, a universal material testing machine and an electrochemical workstation. The results show that the as-cladded AISI 420 stainless steel coating mainly consisted of martensite, austenite, Fe3C and M23C6 carbides. The phase constituent of the coating remained the same, however, the martensite decomposed into finer tempered martensite with the precipitation of numerous nano-sized Fe3C carbides and reverted austenite in the as-tempered specimen. Moreover, a slight reduction was found in the micro-hardness and tensile strength, while a significant increase in elongation was achieved after tempering. The fractography showed a transition from brittle fracture to ductile fracture accordingly. The as-tempered coating exhibited a striking combination of mechanical properties and corrosion resistance. This work can provide a potential strategy to enhance the overall properties of the laser-deposited Fe-based coating for industrial applications.
Zirconium (Zr) is an important alloying element to Mg-Zn-based alloy system. In this paper, we report the formation of the β-type precipitates on the nanoscale Zr-rich particles in a Mg-6Zn-0.5Cu-0.6Zr alloy during ageing at 180°C. Scanning transmission electron microscopy examinations revealed that the nanoscale Zr-rich [0001]α rods/laths are dominant in the Zr-rich core regions of the as-quenched sample after a solution treatment at 430°C. More significantly, these Zr-rich particles served as favourable sites for heterogeneous nucleation of the Zn-rich β-type phase during subsequent isothermal ageing at 180°C. This research provides a potential route to engineer precipitate microstructure for better strengthening effect in the Zr-containing Mg alloys.
Titanium alloys are famous for their light weight, high strength, and heat- and corrosion-resistant properties. However, the excellent mechanical properties are closely related to its microstructure. Innovative machining operations are required for the welding, surface strengthening, and repairs to ensure the refining of the crystalline structure for improved strength requirements, enhanced mechanical properties, and integrating strength. By direct laser melting on the surface of Ti-6Al-4V alloy, the differences of molten pools under continuous and modulated laser mode were compared in the article. Under the same power, the heat influence zone of the laser pool could be reduced to 1/3 of that of the continuous laser. The deep molten pool could be obtained by a continuous laser by the action of high energy density. The tensile property changed a lot between different depths of melt penetration. A high-density, fine-grain molten pool could be obtained under the action of a high-frequency (20 kHz) modulation laser. The mechanical properties of the tensile sample between different depths of melt penetration, which contained the remelting zone, were close to the substrate. The research conclusions can provide technical support for the development of laser remelting processing technology.