Carboxylates constitute an extremely promising class of precursor compounds for the electron beam induced deposition of silver. In this work both silver 2,2-dimethylbutyrate and silver pentafluoropropionate were investigated with respect to their dwell-time-dependent deposition behavior and growth characteristics. While silver 2,2-dimethylbutyrate showed a strong depletion in the center of the impinging electron beam profile hindering any vertical growth, silver pentafluoropropionate indicated a pronounced dependency of the deposit height on the dwell time. Truly three-dimensional silver structures could be realized with silver pentafluoropropionate. The pillars were polycrystalline with silver contents of more than 50 atom % and exhibit strong Raman enhancement. This constitutes a promising route towards the direct electron beam writing of three-dimensional plasmonic device parts from the gas phase.

Approaching the first terawatt of installations, photovoltaics (PV) are about to become the major source of electric power until the mid-century. The technology has proven to be long lasting and very versatile and today PV modules can be found in numerous applications. This is a great success of the entire community, but taking future growth for granted might be dangerous. Scientists have recently started to call for accelerated innovation and cost reduction. Here, we show how ultrathin absorber layers, only a few nanometers in thickness, together with strong light confinement can be used to address new applications for photovoltaics. We review the basics of this new type of solar cell and point out the requirements to the absorber layer material by optical simulation. Furthermore, we discuss innovative applications, which make use of the unique optical properties of the nano absorber solar cell architecture, such as spectrally selective PV and switchable photovoltaic windows.