Possible improvement of the performance characteristics, reliability and selectivity of solid-contact nitrate ion-selective electrodes (ISE) (SC/NO₃⁻-ISE) is attained by the application of a nitron-nitrate (Nit⁺/NO₃⁻) ion association complex and inserting multi-walled carbon nanotubes (MWCNTs) as an ion-to-electron transducer between the ion sensing membrane (ISM) and the electronic conductor glassy carbon (GC) substrate. The potentiometric performance of the proposed electrode revealed a Nernstian slope −55.1 ± 2.1 (r² = 0.997) mV/decade in the range from 8.0 × 10⁻⁸–1 × 10⁻² M with a detection limit of 2.8 × 10⁻⁸ (1.7 ng/mL). Selectivity, repeatability and reproducibility of the proposed sensors were considerably improved as compared to the coated disc electrode (GC/NO₃⁻-ISE) without insertion of a MWCNT layer. Short-term potential stability and capacitance of the proposed sensors were tested using a current-reversal chronopotentiometric technique. The potential drift in presence of a MWCNT layer decreased from 167 μVs⁻¹ (i.e., in absence of MWCNTs) to 16.6 μVs⁻¹. In addition, the capacitance was enhanced from 5.99 μF (in absence of MWCNTs) to 60.3 μF (in the presence of MWCNTs). The presented electrodes were successfully applied for nitrate determination in real samples with good accuracy.

Copper ferrite nano-particles (CuFe₂O₄) were synthesized, characterized, modified with polyaniline to form CuFe₂O₄/PANI nano-composite. They were used as new adsorbents for the removal of the hazardous mercuric ions from aqueous solutions. High resolution transmission electron microscope (HR-TEM), X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) and Brunauer–Emmett–Teller (BET) were used for the characterization of the synthesized CuFe₂O₄ nano-particles (NPs) in presence and absence of PANI nano-composite. The synthesized CuFe₂O₄NPs were of spherical shape with an average size of 10.8 nm. XRD analysis displayed crystal peaks for CuFe₂O₄NPs and amorphous peaks CuFe₂O₄/PANI nano-composite due to the existence of polyaniline layer. Contact time, adsorbent dose, solution pH, adsorption kinetics, adsorption isotherm and recyclability were studied. The method at the optimum conditions exhibited high performance with high mercury removal percentage of up to 99% with a maximum adsorption capacity 12.5 and 157.1 mg/g for CuFe₂O₄ and CuFe₂O₄/PANI, respectively. The adsorption processes were fitted to Langmuir isotherms. The adsorption behavior of CuFe₂O₄@PANI composite towards Hg²⁺ ions is attributed to the soft acid–soft base strong interaction between PANI and Hg(II) ions. High stability and enhanced re-usability are offered using CuFe₂O₄@PANI composite due to its enhanced removal efficiency. No significant removal decrease was noticed after five adsorption–desorption cycles. In addition, it possesses an easy removal from aqueous solutions by external magnetic field after adsorption experiments. These indicated the enhancement of polyaniline to the surface of CuFe₂O₄ toward the adsorption of mercury from aqueous solutions.

A new SnO₂/CeO₂ nano-composite catalyst was synthesized, characterized and used for the removal of alizarin dyes from aqueous solutions. The composite material was prepared using a precipitation method. X-ray powder diffractometry (XRD), high resolution transmission electron microscopy (HR-TEM), Brunauer–Emmett–Teller methodology (BET) and Fourier Transform Infrared Spectrometry (ATR-FTIR) were utilized for the characterization of the prepared composite. The prepared nano-composite revealed high affinity for the adsorption and decomposition of alizarin dyes. The adsorption capacity under different experimental conditions (adsorbate concentration, contact time, adsorbent dose and pH) was examined. Under optimized experimental conditions, the removal of alizarin yellow, alizarin red and alizarin-3-methylimino-diacetic acid dyes from aqueous solutions was about 96.4%,87.8% and 97.3%, respectively. The adsorption isotherms agreed with the models of Langmuir, Freundlich and Temkin isotherms.

Screen-printed membrane sensors based on the use of paper and ceramic substrates are fabricated, characterized, and used for rapid batch and continuous monitoring of Cr^III in the form of CrO₄²⁻ in some industrial products and wastewater samples. Strips of paper and ceramic platforms (15 × 5 mm) were covered with conductive carbon paint and then modified with polyaniline (PANI) film, to act as an ion-to-electron transducer, followed by a drop casting of plasticized poly (vinyl chloride) (PVC) Rhodamine-B chromate membrane as a recognition sensing material. In a 5.0 mmol L⁻¹ Trizma buffer solution of pH ~8, the fabricated paper and ceramic based membrane sensors exhibited a near Nernstian response for Cr^VI ion with slopes of −29.7 ± 0.5 and −28.6 ± 0.3 mV decade⁻¹, limit of detection 2.5 × 10⁻⁵ and 2.4 × 10⁻⁶ mol L⁻¹ (1.3–0.12 µg mL⁻¹), and linear concentration range 7.5 × 10⁻³–5.0 × 10⁻⁵ and 7.5 × 10⁻³–1.0 × 10⁻⁵ mol L⁻¹ (390-0.5 µg mL⁻¹), respectively. Both sensors exhibited fast and stable potentiometric response, excellent reproducibility, and good selectivity with respect to a number of common foreign inorganic species. Impedance spectroscopy and chronopotentiometry data revealed a small resistance and a larger double layer capacitance due to the presence of the intermediate polyaniline (PAN) conductive layer. Furthermore, the formation of a water layer between the ion selective membrane (ISM) and the underlying conductor polymer and between the conducting polymer and the carbon conducting surface was greatly reduced. The developed disposable solid-contact potentiometric sensors offer the advantages of simple design, long term potential stability, flexibility, miniaturization ability, short conditioning time, and cost effectiveness that enable mass production. The sensors were successfully used for static and hydrodynamic measurements of total chromium in some leather tanning wastewater and nickel-chrome alloy samples. The results compare favorably with data obtained by atomic absorption spectrometry.

Herein, we present a new validated potentiometric method for fluoxetine (FLX) drug monitoring. The method is based on the integration of molecular imprinting polymer (MIP) beads as sensory elements with modified screen-printed solid contact ion-selective electrodes (ISEs). A multi-walled carbon nanotube (MWCNT) was used as a nanomaterial for the ion-to-electron transduction process. The prepared MIP beads depend on the use of acrylamide (AAm) and ethylene glycol dimethacrylic acid (EGDMA) as a functional monomer and cross-linker, respectively. The sensor revealed a stable response with a Nernstian slope of 58.9 ± 0.2 mV/decade and a detection limit of 2.1 × 10⁻⁶ mol/L in 10 mmol/L acetate buffer of pH 4.5. The presented miniaturized sensors revealed good selectivity towards FLX over many organic and inorganic cations, as well as some additives encountered in the pharmaceutical preparations. Repeatability, reproducibility and stability have been studied to evaluate the analytical features of the presented sensors. These sensors were successfully applied for FLX assessment in different pharmaceutical formulations collected from the Egyptian local market. The obtained results agreed well with the acceptable recovery percentage and were better than those obtained by other previously reported routine methods.

Herein, we present reliable, robust, stable, and cost-effective solid-contact ion-selective electrodes (ISEs) for perchlorate determination. Single-walled carbon nanotubes (SWCNTs) were used as solid-contact material and indium (III) 5, 10, 15, 20-(tetraphenyl) porphyrin chloride (In^III-porph) as an ion carrier. The sensor exhibited an improved sensitivity towards ClO₄⁻ ions with anionic slope of −56.0 ± 1.1 (R² = 0.9998) mV/decade over a linear range 1.07 × 10⁻⁶ – 1.0 × 10⁻² M and detection limit of 1.8 × 10⁻⁷ M. The short-term potential stability and the double-layer capacitance were measured by chronopotentiometric and electrochemical impedance spectroscopy (EIS) measurements, respectively. The sensor is used for ClO₄⁻ determination in fireworks and propellant powders. The results fairly agree with data obtained by ion chromatography.