Information derived from microscopic images of Li-ion cells is the base for research on the function, the safety, and the degradation of Li-ion batteries. This research was carried out to acquire information required to understand the mechanical properties of Li-ion cells. Parameters such as layer thicknesses, material compositions, and surface properties play important roles in the analysis and the further development of Li-ion batteries. In this work, relevant parameters were derived using microscopic imaging and analysis techniques. The quality and the usability of the measured data, however, are tightly connected to the sample generation, the preparation methods used, and the measurement device selected. Differences in specimen post-processing methods and measurement setups contribute to variability in the measured results. In this paper, the complete sample preparation procedure and analytical methodology are described, variations in the measured dataset are highlighted, and the study findings are discussed in detail. The presented results were obtained from an analysis conducted on a state-of-the-art Li-ion pouch cell applied in an electric vehicle that is currently commercially available.

The deployment of autonomous vehicles on public roads calls for the development of methods that are reliably able to mitigate injury severity in case of unavoidable collisions. This study proposes a data-driven motion planning method capable of minimizing injury severity for vehicle occupants in unavoidable collisions. The method is based on establishing a metric that models the relationship between impact location and injury severity using real accident data, and subsequently including it in the cost function of a motion planning framework. The vehicle dynamics and associated constraints are considered through a precomputed trajectory library, which is generated by solving an optimal control problem. This allows for efficient computation as well as an accurate representation of the vehicle. The proposed motion planning approach is evaluated by simulation, and it is shown that the trajectory associated with the minimum cost mitigates the collision severity for occupants of passenger vehicles involved in the collision.

This study deals with the experimental investigation of the mechanical properties of a lithium-ion pouch cell and its modelling in an explicit finite element simulation code. One can distinguish between ‘macroscopic’ and ‘microscopic’ modelling approaches. In the ‘macroscopic’ approach, one material model approximates the behaviour of multiple inner cell layers. In the ‘microscopic’ approach, which is used in the present study, all layers and their interactions are modelled separately.The cell under study is a pouch-type lithium-ion cell with a liquid electrolyte. With its cell chemistry, design, size and capacity it is usable for automotive applications and can be assembled into traction batteries.One cell sample was fully discharged and disassembled, and its components (anode, cathode, separator and pouch) were examined and measured by electron microscopy. Components were also tensile tested. In this way, each component was fully characterised with respect to the properties needed for explicit finite element models.Multiple quasi-static mechanical tests at different state of charge (SOC) levels under various load cases were conducted. Test results were used to validate the numerical cell model.Simulation of the mechanical behaviour of individual cell layers and the entire cell showed a very reasonable correlation with experimental testing. The developed structural mechanics model for quasi-static load cases is a solid starting point for future analyses, and opens the possibility to predict cell damages with explicit finite element simulations.

Thermal conductivity (TC) is a parameter, which significantly influences the spatial temperature gradients of lithium ion batteries in operative or abuse conditions. It affects the dissipation of the generated heat by the cell during normal operation or during thermal runaway propagation from one cell to the next after an external short circuit. Hence, the thermal conductivity is a parameter of great importance, which concurs to assess the safety of a Li-ion battery. In this work, an already validated, non-destructive measurement procedure was adopted for the determination of the evolution of the through-plane thermal conductivity of 41 Ah commercially available Li-ion pouch cells (LiNiMnCoO₂-LiMn₂O₄/Graphite) as function of battery lifetime and state of charge (SOC). Results show a negative parabolic behaviour of the thermal conductivity over the battery SOC-range. In addition, an average decrease of TC in thickness direction of around 4% and 23% was measured for cells cycled at 60 °C with and without compression, respectively. It was shown that pretension force during cycling reduces battery degradation and thus minimises the effect of ageing on the thermal parameter deterioration. Nevertheless, this study highlights the need of adjustment of the battery pack cooling system due to the deterioration of thermal conductivity after certain battery lifetime with the aim of reducing the risk of battery overheating after certain product life.