Thin film thermoelectric materials (TF TEMs) based on organic semiconductors or organic/inorganic composites exhibit unique properties such as low-temperature processability, mechanical flexibility, great freedom of material design, etc. Thus they have attracted a growing research interest. Similar to inorganic bulk thermoelectric materials (IB TEMs), the Seebeck coefficient combined with electrical conductivity and thermal conductivity is a fundamental property to influence the performance of TF TEMs. However, due to the differences in material and sample geometries, the well-established characterization devices for IB TEMs are no longer applicable to TF TEMs. And until now, a universal standard of measuring the Seebeck coefficient of TF TEMs is still lacking. This mini-review presents the development of instruments designed for measuring the Seebeck coefficient of TF TEMs in the last decade. Primary measurement methods and typical apparatus designs will be reviewed, followed by an error analysis induced by instrumentation. Hopefully this mini-review will facilitate better designs for a more accurate characterization of the Seebeck coefficient of thin film thermoelectric materials.

In this article, we report the preparation of lignin-derived carbon nanosheet (L-CNS) by direct thermal treatment of lignin without activation operation and the functions of the L-CNS as an adsorbent for rhodamine dye. The L-CNSs are fabricated by freeze-drying (FD) methods of lignin followed by high-temperature carbonization. It is found that lower frozen temperature in FD or lower concentration of lignin aqueous solution renders L-CNSs’ more porous morphology and higher specific surface area (SSA), allowing a promising application of the L-CNSs as an efficient adsorbent for organic pollutants. In particular, the alkaline hydroxide catalyst helps to increase the SSA of carbon products, leading to a further improved adsorption capacity. On the other hand, p-toluenesulfonic acid (TsOH) catalyzed pyrolysis, which dramatically increased the L-CNS product yield, and provided a high-yield approach for the production of pollutant absorbent.

Layered double hydroxide with exchangeable interlayer anions are considered promising electro-active materials for renewable energy technologies. However, the limited exposure of active sites and poor electrical conductivity of hydroxide powder restrict its application. Herein, bifunctional integrated electrode with a 3D hierarchical carbon framework decorated by nickel iron-layered double hydroxides (NiFe-LDH) is developed. A conductive carbon nanowire array is introduced not only to provide enough anchoring sites for the hydroxide, but also affords a continuous pathway for electron transport throughout the entire electrode. The 3D integrated architecture of NiFe-hydroxide and hierarchical carbon framework possesses several beneficial effects including large electrochemical active surfaces, fast electron/mass transport, and enhanced mechanical stability. The as-prepared electrode affords a current density of 10 mA cm ⁻² at a low overpotential of 269 mV for oxygen evolution reaction (OER) in 1 M of KOH. It also offers excellent stability with negligible current decline even after 2000 cycles. Besides, density functional theory calculations revealed that the (110) surface of NiFe-LDH is more active than the (003) surface for OER. Furthermore, the electrode possesses promising application prospects in alkaline battery-supercapacitor hybrid devices with a capacity of 178.8 mAh g ⁻¹ (capacitance of 1609.6 F g ⁻¹ ) at a current density of 0.2 A g ⁻¹ . The viability of the as-prepared bifunctional electrode will provide a potential solution for wearable electronics in the near future.