Traditional anti-icing/de-icing systems, i.e., thermal and pneumatic, in most cases require a power consumption not always allowable in small aircraft. Therefore, the use of passive systems, able to delay the ice formation, or reduce the ice adhesion strength once formed, with no additional energy consumption, can be considered as the most promising solution to solve the problem of the ice formation, most of all, for small aircraft. In some cases, the combination of a traditional icing protection system (electrical, pneumatic, and thermal) and the passive coatings can be considered as a strategic instrument to reduce the energy consumption. The effort of the present work was to develop a superhydrophobic coating, able to reduce the surface free energy (SFE) and the work of adhesion (WA) of substrates, by a simplified and non-expensive method. The developed coating, applied as a common paint with an aerograph, is able to reduce the SFE of substrates by 99% and the WA by 94%. The effects of both chemistry and surface morphology on the wettability of surfaces were also studied. In the reference samples, the higher the roughness, the lower the SFE and the WA. In coated samples with roughness ranging from 0.4 and 3 µm no relevant variations in water contact angle, nor in SFE and WA were observed.
Process optimization and quality control are important issues in cold spraying and coating development. Because the cold spray processing is based on high kinetic energy by high particle velocities, online spray monitoring of particle inflight properties can be used as an assisting process tool. Particle velocities, their positions in the spray jet, and particle size measurements give valuable information about spraying conditions. This, in turn, improves reproducibility and reliability of coating production. This study focuses on cold spraying of Al6061 material and the connections between particle inflight properties and coating characteristics such as structures and mechanical properties. Furthermore, novel 2D velocity scan maps done with the HW CS2 online spray monitoring system are presented as an advantageous powder and spray condition controlling tool. Cold spray processing conditions were similar using different process parameters, confirmed with the online spray monitoring prior to coating production. Higher particle velocities led to higher particle deformation and thus, higher coating quality, denser structures, and improved adhesions. Also, deposition efficiency increased significantly by using higher particle velocities.
Intermetallic titanium aluminides have attracted considerable industrial interest for aero and automotive applications owing to their specific strength. These alloys are candidates for high-temperature applications such as turbine blades and turbocharger turbine wheels. In this work, the mechanical behaviour of an as-cast Ti–47Al–3Cr–3Nb (at.-%) alloy was studied. Four-point bending tests were performed to determine the mechanical properties of the alloy at both room and high temperatures. Microhardness and Young's modulus were evaluated by dynamic indentation tests at room temperature. Analyses of the as-cast alloy showed that, with the selected production process conditions, it has a duplex microstructure. Tests revealed that, while at room temperature the alloy is brittle, between 700 and 900°C it exhibits good ductility and mechanical properties.
Biochar has been used in various applications, e.g., as a soil conditioner and in remediation of contaminated water, wastewater, and gaseous emissions. In the latter application, biochar was shown to be a suitable alternative to activated carbon, providing high treatment efficiency. Since biochar is a by-product of waste pyrolysis, its use allows for compliance with circular economics. Thus, this research aims to obtain a detailed characterization of three carbonaceous materials: an activated carbon (CARBOSORB NC 1240®) and two biochars (RE-CHAR® and AMBIOTON®). In particular, the objective of this work is to compare the properties of three carbonaceous materials to evaluate whether the application of the two biochars is the same as that of activated carbon. The characterization included, among others, particle size distribution, elemental analysis, pH, scanning electron microscope, pore volume, specific surface area, and ionic exchange capacity. The results showed that CARBOSORB NC 1240® presented a higher specific surface (1126.64 m2/g) than AMBIOTON® (256.23 m2/g) and RE-CHAR® (280.25 m2/g). Both biochar and activated carbon belong to the category of mesoporous media, showing a pore size between 2 and 50 nm (20–500 Å). Moreover, the chemical composition analysis shows similar C, H, and N composition in the three carbonaceous materials while a higher O composition in RE-CHAR® (9.9%) than in CARBOSORB NC 1240 ® (2.67%) and AMBIOTON® (1.10%). Differences in physical and chemical properties are determined by the feedstock and pyrolysis or gasification temperature. The results obtained allowed to compare the selected materials among each other and with other carbonaceous adsorbents.