The Mesoproterozoic North American Midcontinent Rift hosts the world’s largest accumulation of native copper in Michigan’s Keweenaw Peninsula. During a regional metamorphogenic-hydrothermal event, native copper was deposited along with spatially zoned main-stage minerals in a thermal high. This was followed by deposition of late-stage minerals including minor copper sulfide. Inferences from the oxygen and carbon isotopic composition of main-stage hydrothermal fluids, as calculated from 296 new and compiled isotopic measurements on calcite, are consistent with existing models that low-sulfur saline native copper ore-forming fluids were dominantly derived by burial metamorphic processes from the very low sulfur basalt-dominated rift fill at depth below the native copper deposits. Co-variation of oxygen and carbon isotopic compositions are consistent with mixing of metamorphic-derived fluids with two additional isotopically different fluids. One of these is proposed to be evolved seawater that provided an outside source of salinity. This fluid mixed at depth and participated in the formation of a well-mixed hybrid metamorphic-dominated ore-forming fluid. Secondary Ion Mass Spectrometry in-situ isotopic analyses of calcite demonstrate a high degree of variability within samples that is attributed to variable degrees of shallow mixing of the hybrid ore-forming fluid with sulfur-poor, reduced evolved meteoric water in the zone of precipitation. The oxygen and carbon isotopic compositions of 100 new and compiled measurements on late-stage calcite are mostly isotopically different than the main-stage hydrothermal fluids. The late-stage hydrothermal fluids are interpreted as various proportions of mixing of evolved meteoric water, main-stage hybrid ore-forming fluid, and shallow, evolved seawater in the relatively shallow zone of precipitation.

Changes in magmatism and sedimentation along the late Neoproterozoic-early Paleozoic Ross orogenic belt in Antarctica have been linked to the cessation of convergence along the Mozambique belt during the assembly of East-West Gondwana. However, these interpretations are non-unique and are based, in part, on limited thermochronological data sets spread out along large sectors of the East Antarctic margin. We report new ⁴⁰Ar/³⁹Ar hornblende, muscovite, and biotite age data for plutonic (n = 13) and metasedimentary (n = 3) samples from the Shackleton–Liv Glacier sector of the Queen Maud Mountains in Antarctica. Cumulative ⁴⁰Ar/³⁹Ar age data show polymodal age peaks (510 Ma, 491 Ma, 475 Ma) that lag peaks in U-Pb igneous crystallization ages, suggesting igneous and metamorphic cooling following magmatism within the region. The ⁴⁰Ar/³⁹Ar ages are similar to ages in other sectors of the Ross orogen, but younger than detrital mineral ⁴⁰Ar/³⁹Ar cooling ages indicative of older magmatism and cooling of unexposed inboard areas along the margin. Detrital zircon trace element abundances suggest that the widespread onset of magmatism in outboard localities of the orogen correlates with a ~560–530 Ma decrease in crustal thickness. The timing of crustal thinning recorded by zircon in magmas overlaps with other evidence for the timing of crustal extension, suggesting that the regional onset of magmatism with subsequent igneous and metamorphic cooling probably reflects slab rollback that coincided with possible global plate motion changes induced during the final assembly of Gondwana.

Critical minerals underpin the technologies upon which modern economies now depend, ranging from batteries, magnets, and power electronics to defense systems and digital infrastructure

The 1.1 Ga Mesoproterozoic Midcontinent rift hosts the Eagle, Eagle East, and Tamarack Ni-Cu-PGE deposits and Embayment Prospect. These deposits are hosted by ultramafic igneous rocks and have some of the highest Ni-Cu grades on Earth. We use new bulk-rock data and published datasets (bulk-rock, mineral chemistry, and isotopic analyses) to examine major, minor, and trace element trends of both Midcontinent rift-related alkaline and tholeiitic intrusions. In addition, we compare the geochemical data to local kimberlite-hosted lower-crustal xenoliths and local igneous (Archean) and sedimentary (Paleoproterozoic) country rocks. We found the peridotite magma compositions dominantly consist of primitive mantle compositions with varying abundances of subduction-related components, alkaline-transitional melts, and local country rock contaminates (e.g., Baraga and Animikie Basin sediments). The subduction-related components are interpreted to be derived from previous Archean and Paleoproterozoic subduction events and likely hosted within the sub-continental lithospheric mantle. Importantly, these subduction-related components are also interpreted to have acted as oxidizing agents within the melt, stabilizing sulfate (+2 FMQ (fayalite–magnetite–quartz) to FMQ) while inhibiting sulfide crystallization as the magma ascended through ~50 km of the Superior craton. This study largely corroborates the previous findings with respect to the contribution of local country rock contamination to the Eagle–Tamarack peridotite host rocks, which is estimated to be minimal (<5%). However, the incorporation of <5% reductive pelitic siltstone contamination results in strong shifts in the oxygen fugacity of the peridotite melt, from +2 FMQ to slightly below FMQ, as determined from spinel Fe³⁺/∑Fe ratios. This shift in oxygen fugacity resulted in the transition from total sulfate (+2 FMQ) to sulfate + sulfide (<+2 FMQ to FMQ) to total sulfide (<FMQ). This shift in oxygen fugacity is a key contributor to the formation of Ni-Cu-PGE-rich massive sulfides within the Eagle peridotite. This study presents an expanded geochemical interpretation for the exploration of Midcontinent rift-related Ni-Cu-PGE deposits to include peridotites with subduction-like signatures and contaminated via <5% reductive sedimentary country rocks.