Nowadays, flexible transparent conductive film (FTCF) is one of the important components of many flexible electronic devices. Due to comprehensive performances on optoelectronics, FTCF based on silver nanowires (AgNWs) networks have received great attention and are expected to be a new generation of transparent conductive film materials. Due to its simple process, printed electronic technology is now an important technology for the rapid production of low-cost and high-quality flexible electronic devices. AgNWs-based FTCF fabricated by using printed electronic technology is considered to be the most promising process. Here, the preparation and performance of AgNW ink are introduced. The current printing technologies are described, including gravure printing, screen printing and inkjet printing. In addition, the latest methods to improve the conductivity, adhesion, and stability of AgNWs-based FTCF are introduced. Finally, the applications of AgNWs-based FTCF in solar cells, transparent film heaters, optoelectronic devices, touch panel, and sensors are introduced in detail. Therefore, combining various printing technologies with AgNWs ink may provide more opportunities for the development of flexible electronic devices in the future.

Silver nanowires (AgNWs) show promise for fabricating flexible transparent conductors owing to their excellent conductivity, high transparency, and good mechanical properties. Here, we present the fabrication of transparent films composed of AgNWs with diameters of 20–30 nm and lengths of 25–30 μm on polyethylene terephthalate substrates and glass slides substrates using the Meyer rod method. We systematically investigated the films’ optoelectronic and electrothermal properties. The morphology remained intact when heated at 25–150 °C and the AgNWs film showed high conductivity (17.6–14.3 Ω∙sq⁻¹), excellent transmittance (93.9–91.8%) and low surface roughness values (11.2–14.7 nm). When used as a heater, the transparent AgNW conductive film showed rapid heating at low input voltages owing to a uniform heat distribution across the whole substrate surface. Additionally, the conductivity of the film decreased with increasing bending cycle numbers; however, the film still exhibited a good conductivity and heating performances after repeated bending.

We fabricated graphene-thermopolyurethane (G-TPU) flexible conductive film by a blending method and systematically investigated the electrical, thermal and self-healing properties of the G-TPU flexible conductive film by infrared light and electricity. The experimental results demonstrate that the G-TPU composite films have good conductivity and thermal conductivity in the appropriate mass content of graphene in the composite film. The composite films have the good electro-thermal and infrared light thermal response performances and electro-thermal response performance is closely related to the mass content of graphene in the composite film, but the infrared light thermal response performance is not. The scratch on the composite film can be completely healed, using electricity or infrared light. The healing efficiency of the composite film healed using infrared light is higher than that of using the electricity, while the healing time of the composite film is shorter. Regardless of the self-healing method, the temperature of the self-healing is a very important factor. The self-healing conductive composite film still exhibits a good conductivity.

The inkjet printing process is a promising electronic printing technique for large-scale, printed, flexible and stretchable electronics because of features such as its high manufacturing speed, environmental friendliness, simple process, low cost, accurate positioning, and so on. As the base material of printed conductive patterns, conductive ink is the foundation of the development of printed electronics technology, and directly affects the performance and the quality of electronic products. In this paper, conductive ink with silver nanowires (AgNWs) was prepared, with AgNWs of lengths of 2–5 µm and diameters of 20 nm or so, isopropyl alcohol and ethylene glycol as the mixed solvents, and modified polysilane as the wetting agent. We discussed the relationship between the formula of the AgNWs ink and the surface tension, viscosity, contact angle between ink droplet and poly(ethylene) terephthalate (PET) surface, as well as the film-forming properties of the ink. Further, we analyzed the effects of the number of printed layers and the ink concentration of the AgNWs on the microstructures, photoelectric properties and accuracy of the printed patterns, as well as the change in the sheet resistance of the film during different bending cycles. The experimental results show that flexible transparent conductive patterns with a light transmittance of 550 nm of 83.1–88.4% and a sheet resistance of 34.0 Ω∙sq⁻¹–78.3 nm∙sq⁻¹ can be obtained by using AgNWs ink of 0.38 mg∙mL⁻¹ to 0.57 mg∙mL⁻¹, a poly (ethylene terephthalate) (PET) substrate temperature of 40 °C, a nozzle temperature of 35 °C, and heat treated at 60 °C for 10 min. These performances indicate the excellent potential of the inkjet printing of AgNWs networks for developing flexible transparent conductive film.