Steel slag is a by-product obtained through the separation of molten steel from impurities in steel-making furnaces. It can be produced by different types of furnaces (blast, basic oxygen, electric arc, ladle furnaces). The reuse of metallurgical slags in road pavements can pursue aims of recycling and environmental sustainability. Based on the extensive literature, the paper presents a state-of-the-art review concerning the use of slags in asphalt pavements, discussing the main controversial literature findings. Slag manufacturing processes, chemical, morphological, and physical characteristics, affect its contribution to the asphalt mixture, when it partially or fully substitutes natural aggregates. Legislative state-of-the-art environmental issues, weathering, and leaching aspects are also discussed. The main mechanical and durability properties of pavements containing different types of slags are analyzed based on laboratory and field studies. Generally, the higher mechanical properties of steel slag suggest that its inclusion in asphalt mixtures can provide high-performance pavement layers (excellent strength and stiffness, superior rutting and fatigue resistance, low moisture susceptibility). However, several research gaps still exist (e.g., mix design and seasoning procedure, bitumen–aggregate affinity, low-temperature behavior, brittleness); they are discussed to direct possible future study efforts to clarify specific technical aspects, such as, for example, the effect of slag morphology and physical properties on the final mix properties and the development of specific mix design guidelines.

In a previous work, an ink based on a preceramic polymer, SiC fillers, and chopped carbon fibers was proposed for the production of Ceramic Matrix Composite (CMC) structures by Direct Ink Writing (DIW) and subsequent pyrolysis. Thanks to the shear stresses generated at the nozzle tip during extrusion, carbon fibers can be aligned along the printing direction. Fumed silica was added to the ink in order to enhance its rheological properties; however, the printed structures still showed some deformation in the Z direction. In this work, a second ink was successfully developed to limit deformation and at the same time avoid the addition of fumed silica, which limited the potential temperature of application of the composites. Instead, the positive role of the preceramic polymer on the ink rheology was exploited by increasing its concentration in the ink. Rheological characterization carried out on both inks confirmed that they possessed Bingham shear thinning behavior and fast viscosity recovery. Single filaments with different diameters (~310 µm and ~460 µm) were produced with the latter ink by DIW and subsequent pyrolysis. Tested under a four-point flexural test, the filaments showed a mean flexural strength above 30 MPa, graceful failure, and fiber pull-out. The results of this work suggest that CMC components can effectively be fabricated via DIW of a preceramic ink with embedded short fibers; the preceramic polymer is able to provide the desired rheology for the process and to develop a dense matrix capable of incorporating both fibers and ceramic particles, whereas the fibers addition contributes to an increase of the fracture toughness of the material and to the development of a graceful failure mode.