Admixtures of mineral or waste filling materials are used to reduce slurry density. However, the sheath made of lightweight cement slurry has low mechanical performance at the initial bonding time. The required strength is achieved later. This is the main problem when evaluating the cement bond logging. The waiting time for geophysical measurements after injecting and bonding of cement is nowadays increasingly shortened. This is forced by economic factors. Too early geophysical measurements may result in obtaining a false indication of the cement bond logging. The lack of cement or partial bonding, despite the presence of slurry in the annular space is then found. The slurry developed by the author achieves high compressive strength after a short bonding time. Reducing the amount of water in the slurry resulted in a lowered filtration value. This is important in preventing gas migration after the cementing. The designed slurry also reaches the value of 3.5 MPa in a short time. This allows for an earlier commencement of a well drilling. The use of said slurry improves the effectiveness of the well sealing and makes it possible to obtain a reliable knowledge of the bond logging.
In recent years, graphene-based nanomaterials have been increasingly and widely used in numerous industrial sectors. In the drilling industry, graphene oxide in cement slurry has significantly improved the mechanical parameters of cement composites and is a future-proof solution. However, prior to placing it in a borehole ring space, cement slurry must feature appropriate fluidity. Graphene oxide has a significant influence on rheological parameters. Therefore, it is necessary to study graphene oxide’s influence on the rheological parameters of cement slurries. Thus, this paper presents rheological models and the results of studies on rheological parameters. A basic cement slurry and a slurry with a latex addition were used. The latex admixture was applied at concentrations of 0.1%, 0.03%, and 0.06%. In total, studies were carried out for six slurries with graphene oxide and two basic slurries. The obtained results of studies on the slurries with graphene oxide were compared with the control slurry. It was found that the smallest graphene oxide concentration increased slurry value, some rheological parameter values, plastic viscosity, and the flow limit. Surprisingly, a concentration up to 0.03% was an acceptable value, since the increase in plastic viscosity was not excessively high, which allowed the use of cement slurry to seal the hole. Once this value was exceeded, the slurry caused problems at its injection to the borehole.
The article presents the recipe for ultra-lightweight cement slurry for wellbore sealing. In ordinary lightweight cement slurries, the addition of microspheres and a large amount of water are used to maintain rheological parameters. This is a problem because the light particles of microspheres segregate. The cement sheath from such a cement slurry has an anisotropic microstructure and does not stabilize the casing column. In the new ultra-light cement slurry, 60% aluminosilicate microspheres and a large amount of water were used. The ultra-light weight slurry has a density below 1.2 g/cm3. This cement slurry does not segregates and in the sedimentation stability test has the same density at all measuring points. The cement slurry, despite the larger amount of water, has the same filtration as the control sample. The technological parameters of the slurry are adapted to the borehole conditions. Cement slurry is a ready-made application to seal a borehole with poor wellbore stability under conditions of 40 °C and 10 MPa pressure. The cement sheath structure in the wellbore after binding is homogeneous. The use of such slurry allows to reduce the risk of wall damage in wellbores of poor stability.
Drilling boreholes in gas zones and in zones with the possibility of migration or gas exhalation requires a high index of well tightness. An important parameter determining the effectiveness of sealing the annular space is the adhesion of the cement sheath to the rock formation. Low values of adhesion of the cement sheath to the rock formation and to the casing surface result in the formation of uncontrolled gas flows. The lack of adhesion also reduces the stabilization of the pipe column. To obtain the required adhesion, the annular space should be properly cleaned. Thorough removal of filter cake from the drilling fluid increases adhesion and reduces gas migration from the annular space. Therefore, in this work, the authors focus on determining the effect of cleaning the annular space on the adhesion of the cement sheath to the rock formation. The results of the research work allow for further research on the modification of spacers and cement slurries in order to obtain the required increase in adhesion. The article presents the issues related to the preparation of the borehole for cementing by appropriate cleaning of the rock formation from the residue of the mud cake. During the implementation of the works, tests of cleaning the rock surface are performed. The obtained results are correlated with the results of adhesion on the rock–cement sheath cleaned of the wash mud cake contact. When analyzing the obtained test results, a relationship is found between the cleaning of the rock surface and the adhesion of the cement sheath to it.
Gas migration through fresh and hardened cement slurry is an ongoing problem in the oil industry. In order to eliminate this unfavourable phenomenon, research is being conducted on new compositions of slurries for gas wells. The article presents the results of research for slurries with low and high resistance to gas migration. The proper selection of the quantity and quality of components makes it possible to design slurry with the required static structural strength values. In addition, the cement sheath of such anti-migration slurry has low porosity and a very low proportion of large pore spaces. Additionally, the mechanical parameters do not decrease during long-term deposition in borehole-like conditions. By obtaining these results, it was possible to design slurry whose cement sheath has high corrosion resistance. The new slurry has a lower water-cement ratio. Additionally, GS anti-migration copolymer, anti-filter additive and latex are used. The presence of n-SiO2 aqueous solution and microcement allows for sealing the microstructure of the hardened cement slurry. Such modifications significantly improve the technological parameters of the cement slurry and the cement coat formed from it.