Thin films of Bi₂Te₃ and Sb₂Te₃ were synthesized by the nanoalloying approach, which has recently been proven to yield V–VI compounds with good thermoelectric properties and has several advantages over “conventional” growth on hot substrates. Firstly, repeating layers of the elements Bi, Sb and Te with a thickness in the range between 0.2 nm and 2.4 nm were deposited on BaF₂ (111) substrates in an MBE system at room temperature with different deposition patterns for different samples, i.e. in bilayer and quintuple stacks, with different starting layer thicknesses and different Te contents. Subsequently, the element layer stacks were annealed in order to induce crystallization and compound formation of Bi₂Te₃ and Sb₂Te₃ thin films. The annealed thin films were characterized using X-ray diffractometry (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). The transport properties, i.e. electrical conductivities, carrier concentrations, carrier mobilities, Seebeck coefficients and thermal conductivities, were determined at room temperature for several sets of starting layer thicknesses and deposition patterns depending on the Te content. The texture was found to be strongly influenced by the starting thicknesses of the elemental layers in the deposition pattern. Results of temperature dependent measurements of the Seebeck coefficient and electrical conductivity on one sample of nanoalloyed Bi₂Te₃ and Sb₂Te₃ together with results from temperature dependent in situ XRD investigations are presented.

Electronics (particularly power electronics) are the core element in many energy-related applications. Due to the increasing power density of electronic parts, the demands on thermal management solutions have risen considerably. As a novel passive and highly efficient cooling technology, pulsating heat pipes (PHPs) can transfer heat away from critical hotspots. In this work, we present two types of small and compact PHPs with footprints of 50 × 100 mm², thicknesses of 2 and 2.5 mm and with high fluid channel density, optimized for cooling electronic parts with high power densities. The characterization of these PHPs was carried out with a strong relation to practical applications, revealing excellent thermal properties. The thermal resistance was found to be up to 90% lower than that of a comparable solid copper plate. Thus, a hot part with defined heating power would remain at a much lower temperature level and, for the same heater temperature, a much larger heating power could be applied. Moreover, the dependence of PHP operation and thermal properties on water and air cooling, condenser area size and orientation is examined. Under some test configurations, dryout conditions are observed which could be avoided by choosing an appropriate size for the fluid channels, heater and condenser.

Battery thermal management systems (BTMSs) ensure that lithium-ion batteries (LIBs) in electric vehicles (EVs) are operated in an optimal temperature range to achieve high performance and reduce risks. A conventional BTMS operates either as an active system that uses forced air, water or immersion cooling, or as a complete passive system without any temperature control. Passive systems function without any active energy supply and are therefore economically and environmentally advantageous. However, today’s passive BTMSs have limited cooling performance, which additionally cannot be controlled. To overcome this issue, an innovative BTMS approach based on heat pipes with an integrated thermal switch, developed by the Fraunhofer Cluster of Excellence Programmable Materials (CPM), is presented in this paper. The suggested BTMS consists of switchable heat pipes which couple a passive fin-based cold plate with the battery cells. In cold state, the battery is insulated. If the switching temperature is reached, the heat pipes start working and conduct the battery heat to the cold plate where it is dissipated. The environmental benefits of this novel BTMS approach were then analysed with a Life Cycle Assessment (LCA). Here, a comparison is made between the suggested passive and an active BTMS. For the passive system, significantly lower environmental impacts were observed in nearly all impact categories assessed. It was identified as a technically promising and environmentally friendly approach for battery cooling in EVs of the compact class. Furthermore, the results show that passive BTMS in general are superior from an environmental point of view, due their energy self-sufficient nature.

For many applications, the possibility of controlling heat flow by “thermal switching” could be very beneficial. Several concepts for heat switches were already proposed and tested, however, many drawbacks of these concepts are evident. In this work, we present a novel approach for thermal switching using a water-loaded adsorbent as part of the evaporator of a heat pipe. The basic idea is that the adsorbent releases water upon exceeding a certain evaporator temperature, and thus “activates” the heat pipe by providing the working fluid for thermal transport. The first part of this work concentrates on the adsorbent characterization by analyzing the adsorption isobars and isotherms and thus understanding the behavior of the system. Furthermore, a model to predict the release of water from the adsorbent in dependence of temperature was developed. Subsequently, the adsorbent was integrated into an actual heat pipe demonstrator to verify these predictions and demonstrate the thermal switching ability. Overall results revealed a very good agreement between the predictions concerning water release and the heat pipe’s thermal behavior. The obtained thermal switching ratio depends on the heating power and temperature range that is considered. Depending on whether evaporator/condenser or the adiabatic zone are considered, average switching ratios of circa 3 and 18 were found, respectively.