For many applications, the possibility of controlling heat flow by “thermal switching” could be very beneficial. Several concepts for heat switches were already proposed and tested, however, many drawbacks of these concepts are evident. In this work, we present a novel approach for thermal switching using a water-loaded adsorbent as part of the evaporator of a heat pipe. The basic idea is that the adsorbent releases water upon exceeding a certain evaporator temperature, and thus “activates” the heat pipe by providing the working fluid for thermal transport. The first part of this work concentrates on the adsorbent characterization by analyzing the adsorption isobars and isotherms and thus understanding the behavior of the system. Furthermore, a model to predict the release of water from the adsorbent in dependence of temperature was developed. Subsequently, the adsorbent was integrated into an actual heat pipe demonstrator to verify these predictions and demonstrate the thermal switching ability. Overall results revealed a very good agreement between the predictions concerning water release and the heat pipe’s thermal behavior. The obtained thermal switching ratio depends on the heating power and temperature range that is considered. Depending on whether evaporator/condenser or the adiabatic zone are considered, average switching ratios of circa 3 and 18 were found, respectively.

For many applications, the possibility of controlling heat flow by “thermal switching” can be very beneficial. In previous work, we presented a novel approach for thermal switching using a water-loaded adsorbent as part of the evaporator of a heat pipe. The basic idea is that the adsorbent releases water upon exceeding a certain evaporator temperature and thus “activates” the heat pipe by providing the working fluid for thermal transport. In this work, we present an improved version of the heat switch. We found that an ordinary copper heat pipe (i.e., thermosyphon) with outer diameters common in heat pipe applications (10 mm) can be used as a base of the heat switch. The reversibility of the switching effect was proven. The location of heat input relative to the adsorbent position was optimized, leading to improved switching ratios of up to 36 as calculated from thermal resistance change between evaporator and condenser. Furthermore, the role of the insulation on thermal resistance and switching ratio was examined and found to be significant.

The research project Fraunhofer Cluster of Excellence “Programmable Materials” aims to develop new materials that can change their properties according to defined boundaries. This article describes the development and use of a novel programmable phase change material (PCM) for latent heat storage applications. At the moment, these PCMs have a programmable trigger mechanism incorporated that activates the crystallization of the material as a reaction to a defined stimulus so that the stored heat is released. In future development stages, programmability is to be integrated on the material level. The latent heat storage that is based on PCMs can be recharged by using the energy of the sun. As an example, for a possible application of such a material, the use of a novel programmable PCM in greenhouses to support heating energy reduction or to reduce the risk of frost is explained. Using the hygrothermal simulation tool WUFI^® Plus, the effects in greenhouse constructions without and with commercially available or novel programmable PCMs are calculated and presented in the present article. The calculations are based on the material data of calcium chloride hexahydrate (CaCl₂-6H₂O), as this material serves as a basic material for the development of programmable PCM compositions. The results of the simulations show a positive impact on the indoor temperatures in greenhouses in view of the risk of frost and the reduction of heating energy. Thus, the vegetation period can be extended in combination with a lower energy load. By an eligible actuation mechanism, an inherent material system for temperature control can be created.