LiFePO₄ (lithium iron phosphate, abbreviated as LFP) is a promising cathode material due to its environmental friendliness, high cycling performance, and safety characteristics. On the basis of these advantages, many efforts have been devoted to increasing specific capacity and high rate capacity to satisfy the requirement for next-generation batteries with higher energy density. However, the improvement of LFP capacity is mainly affected by dynamic factors such as low Li-ion diffusion coefficient and poor electrical conductivity. The electrical conductivity and the diffusion of lithium ions can be enhanced by employing novel strategies such as surface modification, particle size-reduction, and lattice substitution (doping), all of which lead to improved electrochemical performance. In addition, cathode pre-lithiation additives have been proved to be quite effective in improving initial capacity for full cell application. The aim of this review paper is to summarize the strategies of capacity enhancement, to discuss the effect of the cathode pre-lithiation additives on specific capacity, and to analyze how the features of LFP (including its structure and phase transformation reaction) influence electrochemical properties. Based on this literature data analysis, we gain an insight into capacity-enhancement strategies and provide perspectives for the further capacity development of LFP cathode material.

The AlCrN and AlCrON coatings were deposited on plasma nitrided H13 steels through ion-source-enhanced arc ion plating, and their structures, mechanical properties, thermal stabilities, and tribological properties were investigated. Structural analysis showed that the monolayer AlCrN and AlCrON bilayered coatings were mainly composed of fcc-AlCrN and fcc-AlCrON solid solution phases respectively. Upon the addition of thin AlCrON layer, the hardness of AlCrN/AlCrON coating slightly decreased from about 30.5 GPa to 28.6 GPa, and the thermal stability was improved after annealing at 700 °C. Both coatings exhibited excellent wear resistance at room temperature, while all wear process involved a combination of wear mechanisms, including severe abrasion and oxidation at an evaluated temperature. The AlCrON bilayered coating showed better wear resistance than that of AlCrN coating due to a dense anti-oxidation layer and better adhesion at a high temperature, making it suitable for die tool protection coatings.