The partial substitution of non-renewable materials in cementitious composites with eco-friendly materials is promising not only in terms of cost reduction, but also in improving the composites’ shielding properties. The water and carbon content of a commercial lignin-based biochar is analyzed with thermal gravimetric analysis. Cementitious composite samples of lignin-based biochar with 14 wt.% and 18 wt.% are realized. Good dispersion of the filler in the composites is observed by SEM analysis. The samples are fabricated in order to fit in a rectangular waveguide for measurements of the shielding effectiveness in the X-band. A shielding effectiveness of 15 dB was obtained at a frequency of 10 GHz in the case of composites with 18 wt.% biochar. Full-wave simulations are performed by fitting the measured shielding effectiveness to the simulated shielding effectiveness by varying material properties in the simulator. Analysis of the dimensional tolerances and thickness of the samples is performed with the help of full/wave simulations. Lignin-based biochar is a good candidate for partial substitution of cement in cementitious composites, as the shielding effectiveness of the composites increases substantially.
Biochar (bio-charcoal) is a low-cost and eco-friendly material. It can be obtained by thermochemical conversion of different biomass sources, for example, in the total absence of oxygen (pyrolysis) or in oxygen-limited atmosphere (gasification). The porous carbonaceous structure of biochar, resulting from the thermal treatment, can be exploited in cement-based composite production. By introducing biochar powder or other fillers in the cement paste, it is possible to enhance the shielding properties of the cement paste. The environmental impact of polyvinyl chloride (PVC) can be reduced by reusing it as a filler in cement-based composites. In this work, cement-based composites filled with different percentages of biochar and PVC are fabricated. The scattering parameters of samples with 4mm thickness are measured by mean of a rectangular waveguide in the C-band. The shielding effectiveness of reference samples without any filler and samples with biochar and PVC is analyzed. A combination of 10 wt.% biochar and 6 wt.% PVC provides the best shielding performance (around 16 dB).
3 August 2021 in Clean Technologies and Environmental Policy
The building sector has a significant impact on the environment due to its unproductive and technologically outdated practices. Although digital tools have emerged as potential solutions, current building practices often lack automation and efficiency. Throughout history, several self-supporting techniques, i.e., construction methods dedicated to the building of shells that do not need support during the construction works, have been developed. These techniques allow for reducing waste and minimizing construction costs. Combining self-supporting techniques and digital tools could aid the development of contemporary, highly sustainable, and efficient building practices that permit the use of alternative and sustainable materials. Building on this, the research conducted defines an approach for evaluating the balanced state of masonry structures during construction works and built using robotic technologies. The approach considers the factors that govern the stability under construction derived through studying self-supporting building techniques. The proposed approach assesses the structural state under construction, evaluating the need for temporary supports. An example of a masonry arch is provided to emphasize the importance of construction factors in sustainable building practices. Then the method is applied to a real case study. Overall, integrating self-supporting techniques with digital tools has the potential to revolutionize the building sector, and create highly sustainable and efficient practices.