The study described in this paper focused on the possible use of waste products coming from the production of styrene–butadiene rubber (SBR) and polybutadiene rubber (PBR), as bitumen modifiers. Modified binders containing these products were prepared in the laboratory with different polymer dosages and were thereafter subjected to the evaluation of empirical and rheological properties. For comparative purposes, the study also considered SBR and PBR products of premium quality. Ageing effects were also taken into account by means of proper laboratory simulations. Obtained results indicated that the two types of polymer (SBR and PBR) have completely different effects on the rheology and expected performance of the resulting modified binders. In particular, while the two polymers showed similar effects in terms of resistance to permanent deformation, the SBR products proved to be superior from the viewpoint of fatigue resistance. However, only minor differences were found when comparing the effects produced by premium quality and waste polymers. As a result of the experimental findings, it was concluded that the use of waste SBR polymers can be an attractive solution for the production of affordable modified binders.
21 May 2024 in Transportation Research Record: Journal of the Transportation Research Board
The study described in this paper aims to establish the relationship between the chemical composition and rheological properties of asphalt binders in both the linear viscoelastic (LVE) and nonlinear viscoelastic (NLVE) domains. Two asphalt binders with different penetration grades were subjected to four distinct aging treatments of varying severity, resulting in changes in their chemical fingerprints. Chemical characteristics of the asphalt binders were analyzed using thin-layer chromatography (TLC), Fourier Transform infrared spectroscopy (FTIR), and gel permeation chromatography (GPC). Frequency sweep tests were conducted to evaluate the LVE behavior of the asphalt binders, while multiple stress creep recovery (MSCR) tests were employed to assess their NLVE properties. With regard to the LVE properties, rheological index ( R ) and zero shear viscosity (ZSV) derived from the Christensen-Anderson-Marasteanu (CAM) model exhibited high correlations with FTIR and molecular weight distribution (MWD) parameters. Additionally, the polydispersity index (PDI) displayed a stronger correlation with LVE-based parameters. Findings from the MSCR tests revealed that the sensitivity of the percentage recovery ( %R ) to chemical composition, as opposed to nonrecoverable creep compliance (
J
nr ), can be largely attributed to the degree of nonlinearity. Furthermore, it was observed that lower molecular weight molecules exert a greater influence on %R in the nonlinear domain. Finally, it was found that
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nrslope is a more reliable parameter than
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nrdiff for assessing the effects of chemical makeup on stress and temperature sensitivity.
1 October 2015 in Proceedings of the Institution of Civil Engineers - Transport
This study set out to estimate the mean speed of passenger cars based on traffic density in two traffic conditions in Tehran, Iran: a homogeneous flow regime in urban highways and a heterogeneous flow regime in suburban highways. Three established models – Greenshields, Greenberg and Underwood – were initially used. However, for higher model compatibility and better mean speed prediction, two new models were proposed. Step-wise regression was used as the statistical analysis for all models and model evaluation was made through multi-collinearity checks, Durbin–Watson tests and coefficients of determination. Results showed poor compatibility of the three established models in a heterogeneous stream and partial compatibility in a homogeneous stream. Using developments of the established models in heterogeneous flow and a new dual-regime model in homogeneous flow, the mean speed could be predicted with higher accuracy and better compatibility.
This paper describes the outcomes of a preliminary study focused on the evaluation of four full-scale pavement sections in which reclaimed asphalt (RAP) was used in partial substitution of virgin aggregates during the production of asphalt mixes. Considered mixes were produced with different RAP percentages and were thereafter laid on site for the formation of asphalt base course layers of pavements in local roads of the State of Qatar. For comparative purposes, two trials included asphalt mixes containing no RAP, and in one case use was made of a rejuvenating agent. Activities carried out for the monitoring of field trials included analysis of component materials, critical observation of production and laying operations, assessment of the most relevant characteristics of produced asphalt mixes, and evaluation of the degree of compaction achieved during construction. Experimental results were of crucial importance for the introduction of RAP-related paving technologies in the State of Qatar, providing a meaningful background to the preparation of the "Ashghal Recycling Manual" issued by Ashghal and of the draft updated version of Qatar Construction Specifications.