The study presented in this paper focused on the use of carbon nanotubes (CNT) in bituminous binders. By employing a single reference base bitumen and multiwall CNTs, several bitumen-CNT blends were prepared at various concentrations and were subjected to rheological characterization in different aging conditions. Results indicate that when CNTs are added with a sufficiently high percentage to base bitumen, they can significantly affect rheological properties. CNTs provide an enhancement of rutting resistance potential and of resistance to thermal cracking. Moreover, susceptibility to oxidative aging is reduced with further advantages that are expected in the long-term performance of bituminous mixtures

Crumb rubber (CR) derived from grinding of end-of-life tyres (ELTs) may be successfully used as a bitumen modifier or as a supplementary component in the production of bituminous mixtures employed for the construction and maintenance of road pavements. However, CRs deriving from different sources and production processes yield effects on performance of corresponding paving mixtures under traffic loading and on gaseous emissions produced during laying on site which may change considerably depending upon their physical and chemical properties. In order to quantitatively assess the possible variability of CR characteristics, 16 samples were taken from 9 Italian and 2 foreign ELT processing plants. Investigation activities included field surveys, during which plants were examined in detail, and laboratory tests, which focused on physical and chemical characterization of CR. Based on the analysis of available technical information and experimental data, it was possible to find relationships between the peculiar characteristics of treatment cycles and corresponding CR properties.

In the experimental study reported in this paper a creep-recovery shear test method was used to evaluate the anti-rutting potential of different polymer-modified bituminous binders. The effects of several factors related to modification were investigated, such as polymer type (SBS, styrene–butadiene–styrene vs. ethylene–vinyl–acetate), composition (styrene content), structure (linear vs. radial SBS) and dosage (3–6 % by weight of the base bitumen). The effect of short-term aging was also considered by comparing binder response before and after treatment with the rolling thin-film oven test. Following previous work on the development of the test protocol, experimental results were analyzed by referring to shear modulus curves G(t) and to permanent compliance (J _P), obtained by dividing residual strain at the end of the unloading phase by the stress applied during creep loading. Results indicated the effectiveness of the proposed method in discriminating between the behavior of the different polymer-modified binders and in capturing the effects caused by the factors considered in the investigation. Reliable rankings of the binders were established and were explained by referring to the specific behavior of employed modifiers.