Department of Building Processes and Building Physics, Faculty of Civil Engineering, Silesian University of Technology, Akademicka 5 St., 44-100 Gliwice, Poland
Dr. Jan Pizoń
Department of Building Processes and Building Physics, Faculty of Civil Engineering, Silesian University of Technology, Akademicka 5 St., 44-100 Gliwice, Poland
Sand has been considered to be something of an immeasurable quantity. There are many indications that this view is no longer valid and that the limiting of natural aggregates usage is doubly justified. Firstly, the extraction of natural aggregates is expensive and has a huge impact on the environment. The main issues in sand and gravel mining are the large areas that are affected, ground water level changes, illegal mining, unsuitability of desert and marine sand, and costs of transport. Secondly, metallurgical waste can be used as a substitute for natural aggregates. This is doubly beneficial—the waste is recycled and the use of natural aggregates is reduced. Waste is stored in landfills that take up large areas and there is also the possibility of ground and groundwater pollution by hazardous compounds. The research presented in this article focuses on the technological conditions of using metallurgical waste in its original form and as a component of recycled concrete aggregate (RCA). The use of metallurgical sludge waste or crushed or round RCA to produce concrete deteriorates the consistency and does not significantly affect the air content and density of the concrete mix. RCA lowers the density of hardened concrete. Metallurgical sludge waste or RCA usage adversely affect the absorbability and permeability of concrete. Concrete containing metallurgical sludge waste is of higher compressive strength after 7 and 28 days, with up to 60% of waste as a sand replacement. RCA concrete achieved higher compressive strength also.
The utilization of metallurgical sludge waste as a 10-30 % replacement of natural sand has been investigated in this paper for its effect on the initial setting time and hydration heat evolution of cement and the mechanical properties of mortars. The results revealed that the addition of metallurgical sludge waste increased the water demand by up to 30 %, delayed the initial setting time by 3 h for 10 %, to over 25 h for 30 % sand replacement, decreased the hydration heat evolution rate by 30 % for 30 % sand replacement, and negatively affected the mortars' mechanical properties from 5 to 40 % for 20 % sand replacement, and from 30 to 50 % for 30 % sand replacement. For 10 % of sand replacement compressive strength was similar to the reference mortar. In order to obtain a shorter initial setting time, decrease the shrinkage and accelerate hydration heat evolution, part of the Portland cement (CEM I) was replaced by calcium sulphoaluminate cement (CSA). It was found that this method was effective for 20-30 % of CEM I replacement by 10 % of CSA and 10-30 % of CEM I replacement by 20-30 % of CSA in the case of setting acceleration, and for 10 % replacement in case of hydration heat evolution.
Reduction of emissions, energy consumption, and use of substitutes for natural resources is an element of sustainable development and the circular economy. Cement production is a process with a high carbon footprint; therefore, minimizing the use of this material has a significant impact on reducing environmental costs. A substitute for cement is municipal solid waste incineration fly ash (MSWIFA). The article presents a method of making an eco-concrete with the use of municipal solid waste incineration hazardous fly ash. The use of secondary waste for the production of building materials additionally contributes to achieving climate neutrality established by the European Union and China. The article analyzes the physicochemical properties of various MSWIFAs, the amount and leachability of heavy metals, and selected elements from MSWIFA and concrete properties. The technical properties of mortars containing MSWIFA were investigated. Consistency is not affected by MSWIFA content, although the workability time is prolonged. Air entraining admixture efficiency is lowered, but the effect lasts longer. The initial setting time is prolonged, and the flexural and compressive strengths are decreased in early terms because of the zinc presence in MSWIFA. MSWIFA does not influence the water demand, volume stability of mortars, or microstructure of cement’s hydration products.
The research presented in this article was conducted to evaluate the suitability of recycled foam concrete (RFC) as an ingredient in newly created cement mortars. The basis for an analysis was the assumption that the waste is collected selectively after separation from other waste generated during demolition. The motivation for the research and its main problem is a comparison of the performance of RFC used in various forms. RFC was used in two forms: (1) recycled foam concrete dust (RFCD) as a 25 and 50% replacement of cement, and (2) recycled foam concrete fine aggregate (RFCA) as a 10, 20, and 30% replacement of sand. The basic properties of fresh and hardened mortars were determined: consistency, density, initial setting time, absorbability, compressive strength, thermal conductivity coefficient, and heat capacity. Research is complemented with SEM observations. The properties of fresh mortars and mechanical parameters were decreased with the usage of any dosage of RFC in any form, but the thermal properties were improved. The required superplasticizer amount for proper consistency was raised four times for replacing cement with 50% of RFCD than for 25% of such replacement. The mix density dropped by about 8% and 9% for mortars with the replacement of 50% cement by RFCD and 30% sand by RFCA in comparison to reference mortar. A 30% decrease in initial setting time was observed for cement replacement. In the case of sand replacement, it was the opposite—an increase of 100%. The dry density decreased by about 14% and 11% for mortars with the replacement of 50% cement by RFCD and 30% sand by RFCA in comparison to reference mortar. Absorbability was raised by about two times after replacement with both RFCD and RFCA. Compressive strength after 28 days dropped significantly by 75% and 60%, and the thermal conductivity coefficient decreased by 20% and 50% with 50% RFCD added instead of cement and 30% RFCA replacing sand. It indicates greater efficiency in thermomechanical means from RFCA in comparison to RFCD. This material can be used especially in the production of plaster and masonry mortar. Linear correlations of dry density and thermal conductivity coefficient and the latter and compressive strength were proven as reliable for RFCD replacement of cement and RFCA replacement of sand in mortars with greater w/c ratio.
The present research compared the behaviours of lightweight mortars based on ordinary Portland cement (OPC), calcium sulphoaluminate cement (CSAC), and calcium aluminate cement (CAC) containing expanded perlite and subjected to elevated temperatures. The perlite substituted natural sand in amounts of 25, 50, 75, and 100% by volume. The mortars were subjected to heating at up to 300 °C, 650 °C, and 1000 °C at a rate of 20 °C/min. The consistency and density of fresh mortars, compressive strength and density of hardened mortars after heating and cooling, and absorbability were assessed. Such a holistic testing approach is the main novelty of this research, which is related to the aforementioned mixtures and elevated temperatures. The main contribution of this article is a comparison of various cement types coupled with variations in the level of sand replacement with expanded perlite. In previous studies, comparisons were made in pairs of OPC-CSAC and OPC-CAC for normal-weight concrete. There is a gap in our knowledge of triple comparisons and lightweight cement composites which is filled by the current study. The use of OPC at up to 650 °C is recommended because it is the most common solution, its performance is similar to that of CAC, and it is cheaper than other solutions. Above 650 °C and up to 1000 °C, CAC is the only solution because it performs better than other cements. CSAC is not suitable for use at elevated temperatures because of its poor strength performance, even if it is the best solution from an environmental point of view. Sand replacement with perlite does not increase the strength performance under elevated temperatures, but its efficiency is different for various types of cement.
This article presents recent research on cements containing GGBFS and their modifications with accelerating admixtures. The initial setting time and hydration heat evolution results are presented for cement CEM II/B-S and CEM III/A manufactured with three Portland clinkers of various phase compositions. The research was carried out at 8 °C and 20 °C. The main objective is to assess the behavior of blended cements in cooperation with modern admixtures that contain nucleation seeds. The authors aimed to compare and evaluate different methods to reduce setting time, namely, the effects of temperature, the specific surface area of cement and GGBFS, the type of Portland clinker, the content of GGBFS, and presence of accelerators. Many of these aspects appear in separate studies, and the authors wanted a more comprehensive coverage of the subject. Those methods of reducing the setting time can be ranked: the most effective is to increase the temperature of the ingredients and the surroundings, the second is to reduce the GGBFS content in cement, and the use of accelerators, and the least effective is the additional milling of Portland clinker. However, of these methods, only the use of accelerators is acceptable in terms of sustainability. Prospective research is a detailed study on the amounts of C-S-H phase and portlandite to determine the hydration rate.