In this work, a flat supported liquid membrane (FSLM) was applied for the extraction of bisphenol A (BPA) from aqueous solutions, using an ionic liquid as a carrier. The liquid membrane consists of tricaprylmethylammonium chloride (aliquat 336^®) diluted in 2-octanol. Furthermore, to obtain the best transport efficiency, the impacts of various experimental parameters were investigated. These parameters included aliquat 336^® concentration, the concentration of BPA in the feed phase, the pH of the feed phase, the concentration of NaOH in the receiving phase, the polymeric support nature, the percentage of extractant in the organic phase, and the solvent nature. The optimum conditions of the experiment were 50% (v/v) aliquat 336^®/2-octanol as the organic phase, a transport time of 8 h, and 1 × 10⁻² mol L⁻¹ NaOH as the receiving phase. The BPA was successfully recovered (the recovery percentage was about 89%). Supported liquid membrane-based aliquat 336^®/2-octanol displayed an acceptable stability with re-impregnation after 5 days of operation.

This study presents the synthesis of Cd_0.5Zn_0.5Fe_2−xCr_xO₄ nanoparticles via the sol–gel method, along with a comprehensive characterization of their morphological, structural, infrared, and magnetic properties. The X-ray diffraction pattern confirms the formation of the spinel structure, and the cation distribution is estimated using X-ray analysis and confirmed by magnetization measurements. The crystalline size, ranging from 152 to 189 nm, and lattice parameter, varying from 8.51134 Å to 8.42067 Å, decrease with increasing Cr content. The saturation magnetization decreases from 55 emu/g to 10.8 emu/g, while the remanent magnetization increases (3.5 emu/g ≤ M_r ≤ 6.27 emu/g), and the coercivity increases (82 Oe ≤ H_C ≤ 422.15 Oe) with the addition of Cr ions. Fourier transform infrared (FTIR) spectroscopy reveals two absorption bands at ν₁ and ν₂, located near 600 and 400 cm⁻¹, respectively, which correspond to the vibrations of the metal–oxygen bonds in the spinel structure.

4-Nitroaniline (PNA) is a toxic organic compound commonly found in wastewater, posing significant environmental concerns due to its toxicity and potential carcinogenicity. In this study, the recovery of PNA from aqueous solutions was investigated using a supported liquid membrane (SLM). The membrane, which consists of polypropylene Celgard 2500 (PP-Celg), was embedded with the extractant tributyl phosphate (TBP). Various factors influencing the efficiency of PNA transportation were studied, including the concentration of PNA in the source phase, pH of the source phase, NaOH concentration in the receiving phase, and choice of stripping agents. Optimal conditions for the experiment were determined to be a source phase PNA concentration of 20 ppm at pH 7, distilled water as the receiving phase, TBP as the carrier in the organic phase, and a transport time of 8 h. The extraction process was conducted under ambient temperature and pressure conditions, yielding results indicative of a first-order linearized reaction. Additionally, membrane stability and liquid membrane loss were evaluated.

Preparation of histidine-conjugated chitosan (His–Cs) adsorbent.