Biomass gasification is a versatile thermochemical process that can be used for direct energy applications and the production of advanced liquid and gaseous energy carriers. In the present work, the results are presented concerning the H₂ production at a high purity grade from biomass feedstocks via steam/oxygen gasification. The data demonstrating such a process chain were collected at an innovative gasification prototype plant coupled to a portable purification system (PPS). The overall integration was designed for gas conditioning and purification to hydrogen. By using almond shells as the biomass feedstock, from a product gas with an average and stable composition of 40%-v H₂, 21%-v CO, 35%-v CO₂, 2.5%-v CH₄, the PPS unit provided a hydrogen stream, with a final concentration of 99.99%-v and a gas yield of 66.4%.

Lignocellulosic biomass is currently widely used in many biorefining processes. The full exploitation of biomass from uncultivated or even marginal lands for the production of biobased chemicals has deserved huge attention in the last few years. Among the sustainable biomass-based value chains, cardoon crops could be a feedstock for biorefineries as they can grow on marginal lands and be used as raw material for multipurpose exploitation, including seeds, roots, and epigeous lignocellulosic solid residue. This work focused on the technical analysis of a novel integrated flowsheet for the exploitation of the lignocellulosic fraction through the assessment of thermochemical, biochemical, and extractive technologies and processes. In particular, high-yield thermochemical processes (gasification), innovative biotechnological processes (syngas fermentation to ethanol), and extractive/catalyzed processes for the valorization of cardoon roots to FDCA and residual solid biomass were modeled and simulated. Inulin conversion to 2,5-Furandicarboxylic acid was the main conversion route taken into consideration. Finally, the novel process flowsheet, treating 130,000 t/y of residual biomass and integrating all proposed technologies, was modeled and assessed using process simulation tools to achieve overall mass and energy balances for comparison with alternative options. The results indicated that cardoon biorefining through the proposed flowsheet can produce, per 1000 tons of input dry biomass, 211 kg of 2,5-Furandicarboxylic acid and 140 kg of ethanol through biomass gasification followed by syngas fermentation. Furthermore, a pre-feasibility analysis was conducted, revealing significant and potentially disruptive results in terms of environmental impact (with 40 kt_CO2eq saved) and economic feasibility (with an annual gross profit of EUR 30 M/y).