Thin films of ZnO and ZnO/carbon nanotubes (CNTs) are prepared and used as CO₂ gas sensors. The spray pyrolysis method was used to prepare both ZnO and ZnO/CNTs films, with CNTs first prepared using the chemical vapor deposition method (CVD). The chemical structure and optical analyses for all the prepared nanomaterials were performed using X-ray diffraction (XRD), Fourier transformer infrared spectroscopy (FTIR), and UV/Vis spectrophotometer devices, respectively. According to the XRD analysis, the crystal sizes of ZnO and ZnO/CNTs were approximately 50.4 and 65.2 nm, respectively. CNTs have average inner and outer diameters of about 3 and 13 nm respectively, according to the transmitted electron microscope (TEM), and a wall thickness of about 5 nm. The detection of CO₂ is accomplished by passing varying rates of the gas from 30 to 150 sccm over the prepared thin-film electrodes. At 150 sccm, the sensitivities of ZnO and ZnO/CNTs sensors are 6.8% and 22.4%, respectively. The ZnO/CNTs sensor has a very stable sensitivity to CO₂ gas for 21 days. Moreover, this sensor has a high selectivity to CO₂ in comparison with other gases, in which the ZnO/CNTs sensor has a higher sensitivity to CO₂ compared to H₂ and C₂H₂.

To improve photoelectrochemical (PEC) water splitting, various ZnO nanostructures (nanorods (NRs), nanodiscs (NDs), NRs/NDs, and ZnO NRs decorated with gold nanoparticles) have been manufactured. The pure ZnO nanostructures have been synthesized using the successive ionic-layer adsorption and reaction (SILAR) combined with the chemical bath deposition (CBD) process at various deposition times. The structural, chemical composition, nanomorphological, and optical characteristics have been examined by various techniques. The SEM analysis shows that by varying the deposition time of CBD from 2 to 12 h, the morphology of ZnO nanostructures changed from NRs to NDs. All samples exhibit hexagonal phase wurtzite ZnO with polycrystalline nature and preferred orientation alongside (002). The crystallite size along (002) decreased from approximately 79 to 77 nm as deposition time increased from 2 to 12 h. The bandgap of ZnO NRs was tuned from 3.19 to 2.07 eV after optimizing the DC sputtering time of gold to 4 min. Via regulated time-dependent ZnO growth and Au sputtering time, the PEC performance of the nanostructures was optimized. Among the studied ZnO nanostructures, the highest photocurrent density (J_ph) was obtained for the 2 h ZnO NRs. As compared with ZnO NRs, the J_ph (7.7 mA/cm²) of 4 min Au/ZnO NRs is around 50 times greater. The maximum values of both IPCE and ABPE are 14.2% and 2.05% at 490 nm, which is closed to surface plasmon absorption for Au NPs. There are several essential approaches to improve PEC efficiency by including Au NPs into ZnO NRs, including increasing visible light absorption and minority carrier absorption, boosting photochemical stability, and accelerating electron transport from ZnO NRs to electrolyte carriers.

A p-n nanocomposite based on TiO₂ nanotubes (NTs) and NiO nanoparticles (NPs) was designed and optimized in this study to improve the photocatalytic performance of methylene blue (MB). The hydrothermal technique has been used to produce TiO₂/NiO nanocomposites with different NiO NPs weight ratios; 1TiO₂:1NiO, 1TiO₂:2NiO, and 1TiO₂:3NiO. The crystal phase, chemical composition, optical properties, and morphology of TiO₂/NiO were explored by various techniques. TiO₂ NTs have a monoclinic structure, while NiO NPs have a cubic structure, according to the structural study. The bandgap of TiO₂ NTs was reduced from 3.54 eV to 2.69 eV after controlling the NiO NPs weight ratio. The TiO₂/2NiO nanocomposite showed the best photodegradation efficiency. Within 45 min of solar light irradiation, the efficiency of MB dye degradation using TiO₂/2NiO hits 99.5% versus 73% using pure TiO₂ NTs. Furthermore, the catalytic photodegradation efficiency did not deteriorate significantly even after five reusability cycles, intimating the high stability of the TiO₂/2NiO nanocomposite. This suggests that the loading of NiO NPs into TiO₂ NTs lowers the recombination of photo-produced electron/hole pairs and enlarged solar spectral response range, which results in improved photocatalytic activity. The mechanism of charge transfer in the TiO₂/NiO and kinetic models were discussed for the photodegradation of MB.