Water is a vital resource that is required for social and economic development. A rapid increase in industrialization and numerous anthropogenic activities have resulted in severe water contamination. In particular, the contamination caused by heavy metal discharge has a negative impact on human health and the aquatic environment due to the non-biodegradability, toxicity, and carcinogenic effects of heavy metals. Thus, there is an immediate need to recycle wastewater before releasing heavy metals into water bodies. Hydrogels, as potent adsorbent materials, are a good contenders for treating toxic heavy metals in wastewater. Hydrogels are a soft matter formed via the cross-linking of natural or synthetic polymers to develop a three-dimensional mesh structure. The inherent properties of hydrogels, such as biodegradability, swell-ability, and functionalization, have made them superior applications for heavy metal removal. In this review, we have emphasized the recent development in the synthesis of hydrogel-based adsorbent materials. The review starts with a discussion on the methods used for recycling wastewater. The discussion then shifts to properties, classification based on various criteria, and surface functionality. In addition, the synthesis and adsorption mechanisms are explained in detail with the understanding of the regeneration, recovery, and reuse of hydrogel-based adsorbent materials. Therefore, the cost-effective, facile, easy to modify and biodegradable hydrogel may provide a long-term solution for heavy metal removal.
1 December 2006 in Polymer Degradation and Stability
All humans and animals need access to clean water in their daily lives. Unfortunately, we are facing water scarcity in several places around the world, and, intentionally or unintentionally, we are contaminating the water in a number of ways. The rise in population, globalization, and industrialization has simultaneously given rise to the generation of wastewater. The pollutants in wastewater, such as organic contaminants, heavy metals, agrochemicals, radioactive pollutants, etc., can cause various ailments as well as environmental damage. In addition to the existing pollutants, a number of new pollutants are now being produced by developing industries. To address this issue, we require some emerging tools and materials to remove effluents from wastewater. Zeolites are the porous aluminosilicates that have been used for the effective pollutant removal for a long time owing to their extraordinary adsorption and ion-exchange properties, which make them available for the removal of a variety of contaminants. However, zeolite alone shows much less photocatalytic efficiency, therefore, different photoactive materials are being doped with zeolites to enhance their photocatalytic efficiency. The fabrication of zeolite-based composites is emerging due to their powerful results as adsorbents, ion-exchangers, and additional benefits as good photocatalysts. This review highlights the types, synthesis and removal mechanisms of zeolite-based materials for wastewater treatment with the basic knowledge about zeolites and wastewater along with the research gaps, which gives a quality background of worldwide research on this topic for future developments.
Lubrication has become essential in enhancing engine efficiency in the era of rapid globalising. The tribological, oxidation and thermal conductivity properties of an engine oil play a vital role in improving the quality of a vehicle’s engine life. In this research, molybdenum disulfide (MoS2) nanoparticle was synthesised via a microwave hydrothermal reactor. Later, the nanoparticles were dispersed in SAE 20W50 diesel engine oil to formulate the nanolubricant. The results show that nanolubricant with 0.01 wt% MoS2 concentration showed the coefficient of friction, average wear scar diameter decreased by 19.24% and 19.52%, respectively, compared to the base oil. Furthermore, the nanolubricant with 0.01 wt% concentration of MoS2 nanoparticle showed an enhancement of 61.15% in oxidation induction time in comparison to the base oil. Furthermore, MoS2 addition within the base oil demonstrates a ~ 10% improvement in thermal conductivity compared to the base oil.
29 January 2011 in Applied Microbiology and Biotechnology
The present research focused on the fabrication of biocompatible polyhydroxyalkanoate, chitosan, and hexagonal boron nitride incorporated (PHA/Ch-hBN) nanocomposites through a simple solvent casting technique. The fabricated nanocomposites were comprehensively characterized by Fourier transform infrared spectroscope (FT-IR), field emission scanning electroscope (FESEM), and elemental mapping and thermogravimetric analysis (TGA). The antibacterial activity of nanocomposites were investigated through time-kill method against multi drug resistant (MDR) microbes such as methicillin-resistant Staphylococcus aureus (MRSA) and Escherichia coli (E. coli) K1 strains. In addition, nanocomposites have examined for their host cytotoxicity abilities using a Lactate dehydrogenase (LDH) assay against spontaneously immortalized human keratinocytes (HaCaT) cell lines. The results demonstrated highly significant antibacterial activity against MDR organisms and also significant cell viability as compared to the positive control. The fabricated PHA/Ch-hBN nanocomposite demonstrated effective antimicrobial and biocompatibility properties that would feasibly suit antibacterial and biomedical applications.