The present research reports the synthesis of ZrO₂-doped TiO₂ photocatalysts at different ZrO₂ contents (1, 3 and 5% wt.) synthesized by the sol–gel method. The samples were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction, attenuated total reflectance-Fourier transform infrared, ultraviolet–visible, X-ray photoelectron spectroscopy and N₂ adsorption–desorption analysis. The photocatalytic activity of the ZrO₂-doped TiO₂ was investigated against the dyes methyl orange and rhodamine B through mineralization studies. The ZrO₂-doped TiO₂ samples presented a semiglobular-ovoid agglomerate shape around 500–800 nm. The samples presented high crystallinity of the TiO₂ anatase phase, XPS suggested the formation of Zr–O–Ti bonds and the samples were classified as mesoporous materials with slight changes in the optical features in comparison with pure TiO₂. Our study shows that the ZrO₂-doped TiO₂ composites exhibited a higher photocatalytic activity than just utilizing the synthetized TiO₂ and a commercial P25. The different degradation behaviors are attributed to differences in the textural properties, and to the different optical absorptions of the samples due to structural defects created by the level of doping of Zr⁴⁺ ions into the TiO₂ lattice. Reaction kinetics parameters were calculated by the Langmuir–Hinshelwood model, and a third run cycle of the ZrO₂-doped TiO₂ at 1% wt. achieved a photocatalytic degradation of 78.1 and 75.5% for RhB and MO, respectively.

Zinc nitrate (ZnO_N) and zinc acetate (ZnO_A) were used as precursors for the synthesis of zinc oxide (ZnO) nanoparticles by the sol–gel method. The ZnO powder was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy, X-ray diffraction (UV–Vis DRS), Fourier transform infrared spectroscopy (FTIR), physisorption of nitrogen, and X-ray photoelectron spectroscopy (XPS). On the other hand, the photocatalytic activity of the samples was tested in the degradation of 2,4-Dichlorophenoxyacetic acid (2,4-D) and 2,4-Dichlorophenol (2,4-DCP) under UV-light irradiation. The ZnO_N and ZnO_A showed polycrystalline irregular structures and rod-like morphology with mean sizes of 40 and 99 nm, respectively. The precursor type influenced the bandgap, crystallite size, surface area, total pore volume, and pore diameter. The XPS results showed high contents of C and N in the ZnO samples, and as a consequence, the solids present remarkable differences in the C/N, O/C, and O/Zn atomic ratios, which significantly influenced the physicochemical characteristics. The ZnO_N and ZnO_A exhibit photocatalytic properties against 2,4-D (74.7 and 90.9%, respectively) and 2,4-DCP (78.4 and 86.7%, respectively) and better performance of ZnO_A. These results are promising and indicate the potential to use this material as a photocatalyst to degrade organic pesticides.

Mixed oxide nanoparticles (MONs, TiO₂–ZnO–MgO) obtained by the sol-gel method were characterized by transmission electron microscopy, (TEM, HRTEM, and SAED) and thermogravimetric analysis (TGA/DTGA–DTA). Furthermore, the effect of MONs on microbial growth (growth profiling curve, lethal and sublethal effect) of Escherichia coli, Salmonella paratyphi, Staphylococcus aureus and Listeria monocytogenes, as well as the toxicity against Artemia salina by the lethal concentration test (LC₅₀) were evaluated. MONs exhibited a near-spherical in shape, polycrystalline structure and mean sizes from 17 to 23 nm. The thermal analysis revealed that the anatase phase of MONs is completed around 480–500 °C. The normal growth of all bacteria tested is affected by the MONs presence compared with the control group. MONs also exhibited a reduction on the plate count from 0.58 to 2.10 log CFU/mL with a sublethal cell injury from 17 to 98%. No significant toxicity within 24 h was observed on A. salina. A bacteriostatic effect of MONs on bacteria was evidenced, which was strongly influenced by the type of bacteria, as well as no toxic effects (LC₅₀ >1000 mg/L; TiO₂–ZnO (5%)–MgO (5%)) on A. salina were detected. This study demonstrates the potential of MONs for industrial applications.

The indiscriminate use of naproxen as an anti-inflammatory has been the leading cause of pollution in sewage effluents. Conversely, titanium dioxide is one of the most promising photocatalyst for the degradation of pollutants. Ti-La mixed oxides containing 0, 1, 3, 5, and 10 wt.% of lanthanum were synthetized by sol-gel and tested as photocatalysts in the degradation of naproxen (NPX). The materials were further characterized by X-ray diffraction (XRD), nitrogen physisorption (BET), scanning electron microscopy (SEM), UV-Vis and Fourier-transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The XRD patterns resembled that of anatase titania. The Eg values, determined from the UV-Vis spectra, vary from 2.07 to 3.2 eV corresponded to pure titania. The photocatalytic activity of these materials showed a degradation of naproxen from 93.6 to 99.8 wt.% after 4 h under UV irradiation.