The quality of water is continuously under threat as increasing concentrations of pollutants escape into the aquatic environment. However, these issues can be alleviated by adsorbing pollutants onto adsorbents. Chitosan and its composites are attracting considerable interest as environmentally acceptable adsorbents and have the potential to remove many of these contaminants. In this review the development of chitosan-based adsorbents is described and discussed. Following a short introduction to the extraction of chitin from seafood wastes, followed by its conversion to chitosan, the properties of chitosan are described. Then, the emerging chitosan/carbon-based materials, including magnetic chitosan and chitosan combined with graphene oxide, carbon nanotubes, biochar, and activated carbon and also chitosan-silica composites are introduced. The applications of these materials in the removal of various heavy metal ions, including Cr(VI), Pb(II), Cd(II), Cu(II), and different cationic and anionic dyes, phenol and other organic molecules, such as antibiotics, are reviewed, compared and discussed. Adsorption isotherms and adsorption kinetics are then highlighted and followed by details on the mechanisms of adsorption and the role of the chitosan and the carbon or silica supports. Based on the reviewed papers, it is clear, that while some challenges remain, chitosan-based materials are emerging as promising adsorbents.

Chitosan is a natural polymer that has been employed in dye adsorption. In this work, adsorption and thermodynamic data for the interaction of FD&C Red n° 40 food dye with chitosan in aqueous solutions were investigated. The equilibrium adsorption isotherms were determined by the batch method, from 298 to 338 K. Adsorption data were adjusted to five isotherm models: Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich, in order to determine which presented the best adjustment to the experimental data. Error analysis showed that the Langmuir isotherm model was the most appropriate for fitting the experimental data, with a maximum monolayer adsorption of 3065.8 µmol g-1 at 308 K. Negative enthalpy (-112.7 kJ mol-1), entropy (-0.338 kJ mol-1 K-1) and Gibbs free energy (-15.6 to 1.0 kJ mol-1) values demonstrated that the adsorption process is exothermic, spontaneous, favorable, and that randomness of the system decreases during the adsorption process