Liquid crystals are an integral part of a mature display technology, also establishing themselves in other applications, such as spatial light modulators, telecommunication technology, photonics, or sensors, just to name a few of the non-display applications. In recent years, there has been an increasing trend to add various nanomaterials to liquid crystals, which is motivated by several aspects of materials development. (i) addition of nanomaterials can change and thus tune the properties of the liquid crystal; (ii) novel functionalities can be added to the liquid crystal; and (iii) the self-organization of the liquid crystalline state can be exploited to template ordered structures or to transfer order onto dispersed nanomaterials. Much of the research effort has been concentrated on thermotropic systems, which change order as a function of temperature. Here we review the other side of the medal, the formation and properties of ordered, anisotropic fluid phases, liquid crystals, by addition of shape-anisotropic nanomaterials to isotropic liquids. Several classes of materials will be discussed, inorganic and mineral liquid crystals, viruses, nanotubes and nanorods, as well as graphene oxide.

Compatible green polymer electrolytes based on methyl cellulose (MC) were prepared for energy storage electrochemical double-layer capacitor (EDLC) application. X-ray diffraction (XRD) was conducted for structural investigation. The reduction in the intensity of crystalline peaks of MC upon the addition of sodium iodide (NaI) salt discloses the growth of the amorphous area in solid polymer electrolytes (SPEs). Impedance plots show that the uppermost conducting electrolyte had a smaller bulk resistance. The highest attained direct current DC conductivity was 3.01 × 10⁻³ S/cm for the sample integrated with 50 wt.% of NaI. The dielectric analysis suggests that samples in this study showed non-Debye behavior. The electron transference number was found to be lower than the ion transference number, thus it can be concluded that ions are the primary charge carriers in the MC–NaI system. The addition of a relatively high concentration of salt into the MC matrix changed the ion transfer number from 0.75 to 0.93. From linear sweep voltammetry (LSV), the green polymer electrolyte in this work was actually stable up to 1.7 V. The consequence of the cyclic voltammetry (CV) plot suggests that the nature of charge storage at the electrode–electrolyte interfaces is a non-Faradaic process and specific capacitance is subjective by scan rates. The relatively high capacitance of 94.7 F/g at a sweep rate of 10 mV/s was achieved for EDLC assembly containing a MC–NaI system.

Graphene oxide (GO) nanoparticles of two different sizes are dispersed in the nematic liquid crystal (LC) 5CB covering a wide concentration range. The dielectric properties, as well as the electrooptic behavior, including threshold voltage, elastic constant, and response times are investigated as a function of GO concentration. It is found that small graphene oxide flakes of mean size of 560 nm are better and easier dispersible than larger flakes of 2.8 μm mean size. The nematic–isotropic transition only increases slightly for the (GO+LC) hybrid systems. For increasing GO concentrations the threshold voltage and splay elastic constant dramatically increase, until saturation for a concentration of ≈1% by weight GO. The field driven switching‐on time is practically independent of concentration, while the switching‐off time, which is purely elastically driven, exhibits a strongly decreasing behavior. Dielectric spectroscopy reveals a noncollective relaxation which is absent in the neat liquid crystal. This may be attributed to a drastically slowed down molecular relaxation related to the rotation around the short axis of the liquid crystal molecules. When heating the thermotropic liquid crystal into its isotropic phase, the latter acts as a solvent for the GO particles, and a lyotropic nematic phase with largely reduced birefringence is formed.

In this work, plasticized magnesium ion-conducting polymer blend electrolytes based on chitosan:methylcellulose (CS:MC) were prepared using a solution cast technique. Magnesium acetate [Mg(CH₃COO)₂] was used as a source of the ions. Nickel metal-complex [Ni(II)-complex)] was employed to expand the amorphous phase. For the ions dissociation enhancement, glycerol plasticizer was also engaged. Incorporating 42 wt% of the glycerol into the electrolyte system has been shown to improve the conductivity to 1.02 × 10⁻⁴ S cm⁻¹. X-ray diffraction (XRD) analysis showed that the electrolyte with the highest conductivity has a minimum crystallinity degree. The ionic transference number was estimated to be more than the electronic transference number. It is concluded that in CS:MC:Mg(CH₃COO)₂:Ni(II)-complex:glycerol, ions are the primary charge carriers. Results from linear sweep voltammetry (LSV) showed electrochemical stability to be 2.48 V. An electric double-layer capacitor (EDLC) based on activated carbon electrode and a prepared solid polymer electrolyte was constructed. The EDLC cell was then analyzed by cyclic voltammetry (CV) and galvanostatic charge–discharge methods. The CV test disclosed rectangular shapes with slight distortion, and there was no appearance of any redox currents on both anodic and cathodic parts, signifying a typical behavior of EDLC. The EDLC cell indicated a good cyclability of about (95%) for throughout of 200 cycles with a specific capacitance of 47.4 F/g.

The electro-optic and dielectric properties of barium titanate, BaTiO₃, and nanoparticle (NP) doped nematic and ferroelectric liquid crystal materials were examined with respect to different size and concentrations of the NPs. Smaller size paraelectric NPs (≈80 nm) are compared to larger, ferroelectric NPs (≈240 nm). It is found that for concentrations larger than 0.5 vol. %, the ferroelectric NPs exhibit an increasing effect on the electro-optic response of the nematic liquid crystal, which is demonstrated by the enhancement of the dielectric anisotropy. This could be induced by the coupling of the electrical dipole moments in the spherical NPs with the LC director field. The electro-optical properties of the SmC* phase, such as the tilt angle Θ, switching time ${\tau }_s$ , and spontaneous polarisation $\hspace{0.17em}{P}_s$ , are found to be independent of the concentration and size of the NPs. The rotational viscosity $\eta$ calculated from response times, polarization reversal current, and dielectric properties is comparable for all three methods employed and practically independent of particle concentration and size. The relaxation frequency $f_R$ of the Goldstone mode is higher in the ferroelectric NPs suspensions of 2.0 vol. % as compared to the smaller paraelectric NPs.

In this work, analysis of ion transport parameters of polymer blend electrolytes incorporated with magnesium trifluoromethanesulfonate (Mg(CF₃SO₃)₂) was carried out by employing the Trukhan model. A solution cast technique was used to obtain the polymer blend electrolytes composed of chitosan (CS) and poly (2-ethyl-2-oxazoline) (POZ). From X-ray diffraction (XRD) patterns, improvement in amorphous phase for the blend samples has been observed in comparison to the pure state of CS. From impedance plot, bulk resistance (R_b) was found to decrease with increasing temperature. Based on direct current (DC) conductivity (σ_dc) patterns, considerations on the ion transport models of Arrhenius and Vogel–Tammann–Fulcher (VTF) were given. Analysis of the dielectric properties was carried out at different temperatures and the obtained results were linked to the ion transport mechanism. It is demonstrated in the real part of electrical modulus that chitosan-salt systems are extremely capacitive. The asymmetric peak of the imaginary part (M_i) of electric modulus indicated that there is non-Debye type of relaxation for ions. From frequency dependence of dielectric loss (ε″) and the imaginary part (M_i) of electric modulus, suitable coupling among polymer segmental and ionic motions was identified. Two techniques were used to analyze the viscoelastic relaxation dynamic of ions. The Trukhan model was used to determine the diffusion coefficient (D) by using the frequency related to peak frequencies and loss tangent maximum heights (tanδ_max). The Einstein–Nernst equation was applied to determine the carrier number density (n) and mobility. The ion transport parameters, such as D, n and mobility (μ), at room temperature, were found to be 4 × 10⁻⁵ cm²/s, 3.4 × 10¹⁵ cm⁻³, and 1.2 × 10⁻⁴ cm²/Vs, respectively. Finally, it was shown that an increase in temperature can also cause these parameters to increase.