Biofuel heaters and fireplaces have in recent years been introduced for indoor and outdoor use. Due to their simplicity, they are usually equipped with few or no safety features. Worldwide, incidents resulting in major skin burn injury and long hospitalization periods have occurred when using such biofuel units. The present study analyses the characteristics of the liquids ethanol and methanol to get a scientific background for understanding related accidents. The comparably heavy vapors, especially from ethanol, may generate a pillow of combustible gas in the vicinity of the unit, particularly in quiescent indoor air conditions. It is also revealed that these fuels represent a potential severe risk, since the equilibrium vapor pressures are close to the stoichiometric fuel–air composition at normal room temperatures. Selected incidents were reviewed to understand the mechanisms involved when severe burns were received by the users. It turns out that the most severe incidents were related to refilling operations and included ignition of the fuel container vapor phase. When ignited, the container gas phase expansion propelled burning fuel from the bottle or container onto the user or other persons in the vicinity. Similar incidents involving refilling methanol for chemistry demonstrations and ethanol for endodontic (dentistry) treatment were also studied and it was shown that these accidents followed similar accident mechanisms. It may be concluded that the main contributors to burn risk are the near-stoichiometric vapor pressure of these liquids at room temperature and the close proximity of the fuel container to burning fuel. Research needs and possible technical barriers are suggested to reduce this risk for the future.
The transient hot‐strip (THS) method has been modified to measure thermal conductivity of small test specimens. The conventional metal strip used simultaneously as the heater and the temperature sensor was substituted with a 50‐Ω commercial temperature sensor (grid 5.85 mm×6.35 mm). The short transient hot‐strip (STHS) method was tested on Pyrex 7740, stainless steel (NIST 1462 standard reference material), and aluminum to cover more than two orders of magnitude in thermal conductivity. The STHS method agreed with conventional measurement techniques within 3% in the thermal conductivity range 1–200 W m−1 K−1.
Parameters leading to the severity of the fire in Lærdalsøyri, Norway, January 18th to 19th 2014, have been analyzed. The fire in the first villa developed significantly faster than the fire fighters could handle and the fire quickly spread to other structures. In addition to 36 modern buildings, 4 historic buildings in Gamle Lærdalsøyri cultural heritage area were lost. Heroic effort of local and neighbor community fire brigades, police, military forces and volunteers prevented the fire from destroying the whole village, including the remaining 157 historic buildings. Adiabatically heated (low humidity) air from surrounding high mountains gave outdoor wood fuel moisture content (FMC) of about 7.6%. Inside inhabited buildings, it is shown that the wooden products reached about 4.5% FMC prior to the blaze. When ignited, this resulted in rapid fire development. Two story villas burned down in less than 1 h while producing much embers and firebrands. Strong shifting winds subsequently spread the fire to neighbor houses by flame contact (periodically 20 m long horizontal flames) and over long distances (200 m) by embers and firebrands. Based on the present work, an increased fire risk associated with low FMC in inhabited wooden houses during winter time can be predicted. This is of value when considering measures to reduce the probability of a fire outbreak as well as measures mitigating the escalation of a potential fire.